CAS 486429-99-6|(S)-1,13-Bis(diphenylphosphino)-7,8-dihydro-6H-dibenzo[f,h][1,5]dioxonine
Introduction：Basic information about CAS 486429-99-6|(S)-1,13-Bis(diphenylphosphino)-7,8-dihydro-6H-dibenzo[f,h][1,5]dioxonine, including its chemical name, molecular formula, synonyms, physicochemical properties, and safety information, etc.
| Common Name | (S)-1,13-Bis(diphenylphosphino)-7,8-dihydro-6H-dibenzo[f,h][1,5]dioxonine | ||
|---|---|---|---|
| CAS Number | 486429-99-6 | Molecular Weight | 594.61800 |
| Density | / | Boiling Point | 709.9±60.0 ℃(Predicted) |
| Molecular Formula | C39H32O2P2 | Melting Point | 153-161ºC(lit.) |
| MSDS | ChineseUSA | Flash Point | / |
Names
| Name | (S)-C3-TunePhos |
|---|---|
| Synonym | More Synonyms |
Chemical & Physical Properties
| Boiling Point | 709.9±60.0 ℃(Predicted) |
|---|---|
| Melting Point | 153-161ºC(lit.) |
| Molecular Formula | C39H32O2P2 |
| Molecular Weight | 594.61800 |
| Exact Mass | 594.18800 |
| PSA | 45.64000 |
| LogP | 7.03130 |
Safety Information
| Personal Protective Equipment | Eyeshields;Gloves;type N95 (US);type P1 (EN143) respirator filter |
|---|---|
| Hazard Codes | Xi |
| RIDADR | NONH for all modes of transport |
| WGK Germany | 3 |
Articles3
More Articles| Synthesis of chiral bisphosphines with tunable bite angles and their applications in asymmetric hydrogenation of beta-ketoesters. J. Org. Chem. 65 , 6223, (2000) | |
| Enantioselective hydrogenation of tetrasubstituted olefins of cyclic beta-(acylamino)acrylates. J. Am. Chem. Soc. 125 , 9570, (2003) Hydrogenation of a series of cyclic beta-(acylamino)acrylates with tetrasubstituted olefins has been accomplished successfully with the use of Ru catalysts with chiral biaryl ligands such as C3-TunaPh... | |
| Highly enantioselective asymmetric hydrogenation of alpha-phthalimide ketone: an efficient entry to enantiomerically pure amino alcohols. J. Am. Chem. Soc. 126 , 1626, (2004) A new type of alpha-phthalimide ketones was hydrogenated in excellent enantioselectivity by using a Ru-(C3-TunePhos) complex as the catalyst. Up to 10 000 turnovers have been achieved in more than 99%... |
Synonyms
| (S)-(+)-1,13-Bis(diphenylphosphino)-7,8-dihydro-6H-dibenzo[f,h][1,5]dioxonin, 95% (S)-C3-TUNEPHOS |
| MFCD06658115 |
