Introduction：Basic information about CAS 880262-14-6|[(1,2,5,6-eta)-1,5-Cyclooctadiene][1-[(4R,5R)-4,5-dihydro-5-methyl-2-phenyl-4-oxazol, including its chemical name, molecular formula, synonyms, physicochemical properties, and safety information, etc.
| Common Name | [(1,2,5,6-eta)-1,5-Cyclooctadiene][1-[(4R,5R)-4,5-dihydro-5-methyl-2-phenyl-4-oxazolyl]-2-phenyl-1-(phenylmethyl)ethyl dicyclohexylphosphinite]iridium tetrakis[3,5-bis(trifluoromethyl)phenyl]borate |
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| CAS Number | 880262-14-6 | Molecular Weight | 1747.35000 |
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| Density | / | Boiling Point | / |
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| Molecular Formula | C77H70BF24IrNO3P | Melting Point | 160-161°C |
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| MSDS | USA | Flash Point | / |
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Names
| Name | [(1,2,5,6-eta)-1,5-Cyclooctadiene][1-[(4R,5R)-4,5-dihydro-5-methyl-2-phenyl-4-oxazolyl]-2-phenyl-1-(phenylmethyl)ethyl dicyclohexylphosphinite]iridium tetrakis[3,5-bis(trifluoromethyl)phenyl]borate |
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| Synonym | More Synonyms |
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Chemical & Physical Properties
| Melting Point | 160-161°C |
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| Molecular Formula | C77H70BF24IrNO3P |
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| Molecular Weight | 1747.35000 |
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| Exact Mass | 1747.44000 |
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| PSA | 57.70000 |
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| LogP | 22.72760 |
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| Appearance of Characters | Powder |
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| InChIKey | LADOFGASZSKWMF-XQVJCUDVSA-N |
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| SMILES | C1=CCCC=CCC1.CC1OC(c2ccccc2)=NC1C(Cc1ccccc1)(Cc1ccccc1)OP(C1CCCCC1)C1CCCCC1.FC(F)(F)c1cc([B-](c2cc(C(F)(F)F)cc(C(F)(F)F)c2)(c2cc(C(F)(F)F)cc(C(F)(F)F)c2)c2cc(C(F)(F)F)cc(C(F)(F)F)c2)cc(C(F)(F)F)c1.[Ir] |
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Safety Information
| Personal Protective Equipment | Eyeshields;Gloves;type N95 (US);type P1 (EN143) respirator filter |
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| RIDADR | NONH for all modes of transport |
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Articles2
More Articles
| A New Class of Modular Phosphinite-Oxazoline Ligands: Ir-Catalyzed Enantioselective Hydrogenation of Alkenes We thank Dr. Martin Studer and Dr. Beno_t Pugin (Solvias AG, Basel) for fruitful discussions, and Prof. Kevin Burgess (Texas A&M University) for preprints of related unpublished work. Financial support by the Swiss National Science Foundation is gratefully acknowledged. Angew. Chem. Int. Ed. Engl. 40 , 4445-4447, (2001)
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| Threonine-derived phosphinite-oxazoline ligands for the Ir-catalyzed enantioselective hydrogenation. Menges, F. and Pfaltz, A. Adv. Synth. Catal. 344 , 40-44, (2002)
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Synonyms
