CAS 100-99-2|Triisobutylaluminum
| Common Name | Triisobutylaluminum | ||
|---|---|---|---|
| CAS Number | 100-99-2 | Molecular Weight | 198.324 |
| Density | 0.848 g/mL at 25 °C | Boiling Point | 68-69 °C |
| Molecular Formula | C12H27Al | Melting Point | 4-6°C |
| MSDS | ChineseUSA | Flash Point | −1 °F |
| Symbol | GHS02, GHS05 | Signal Word | Danger |
Names
| Name | Triisobutylaluminium |
|---|---|
| Synonym | More Synonyms |
Chemical & Physical Properties
| Density | 0.848 g/mL at 25 °C |
|---|---|
| Boiling Point | 68-69 °C |
| Melting Point | 4-6°C |
| Molecular Formula | C12H27Al |
| Molecular Weight | 198.324 |
| Flash Point | −1 °F |
| Exact Mass | 198.192810 |
| LogP | 4.83000 |
| Index of Refraction | 1.4494 |
| InChIKey | MCULRUJILOGHCJ-UHFFFAOYSA-N |
| SMILES | CC(C)C[Al](CC(C)C)CC(C)C |
| Water Solubility | reacts |
Toxicological Information
CHEMICAL IDENTIFICATION |
ACUTE TOXICITY DATA - TYPE OF TEST :
- LDLo - Lowest published lethal dose
- ROUTE OF EXPOSURE :
- Oral
- SPECIES OBSERVED :
- Rodent - rat
- DOSE/DURATION :
- 4 gm/kg
- TOXIC EFFECTS :
- Gastrointestinal - other changes
- REFERENCE :
- NTIS** National Technical Information Service. (Springfield, VA 22161) Formerly U.S. Clearinghouse for Scientific & Technical Information. Volume(issue)/page/year: OTS0555398
- TYPE OF TEST :
- LCLo - Lowest published lethal concentration
- ROUTE OF EXPOSURE :
- Inhalation
- SPECIES OBSERVED :
- Rodent - rat
- DOSE/DURATION :
- 8000 ppm/1H
- TOXIC EFFECTS :
- Sense Organs and Special Senses (Olfaction) - effect, not otherwise specified Behavioral - somnolence (general depressed activity) Lungs, Thorax, or Respiration - dyspnea
- REFERENCE :
- NTIS** National Technical Information Service. (Springfield, VA 22161) Formerly U.S. Clearinghouse for Scientific & Technical Information. Volume(issue)/page/year: OTS0555398 *** REVIEWS *** ACGIH TLV-TWA 2 mg(Al)/m3 DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices (BEIs) booklet issues by American Conference of Governmental Industrial Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year: TLV/BEI,1997 *** OCCUPATIONAL EXPOSURE LIMITS *** OEL-AUSTRALIA:TWA 2 mg(Al)/m3 JAN 1993 OEL-BELGIUM:TWA 2 mg(Al)/m3 JAN 1993 OEL-DENMARK:TWA 2 mg(Al)/m3 JAN 1993 OEL-FRANCE:TWA 2 mg(Al)/m3 JAN 1993 OEL-THE NETHERLANDS:TWA 2 mg(Al)/m3 JAN 1993 OEL-RUSSIA:TWA 2 mg(Al)/m3 JAN 1993 OEL-SWEDEN:TWA 2 mg(Al)/m3 JAN 1993 OEL-SWITZERLAND:TWA 2 mg(Al)/m3 JAN 1993 OEL-UNITED KINGDOM:TWA 2 mg(Al)/m3 JAN 1993 OEL IN BULGARIA, COLOMBIA, JORDAN, KOREA check ACGIH TLV OEL IN NEW ZEALAND, SINGAPORE, VIETNAM check ACGIH TLV *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOHS - National Occupational Hazard Survey (1974) NOHS Hazard Code - 82975 No. of Facilities: 20 (estimated) No. of Industries: 1 No. of Occupations: 13 No. of Employees: 5089 (estimated)
Safety Information
| Symbol | GHS02, GHS05 |
|---|---|
| Signal Word | Danger |
| Hazard Statements | H250-H260-H314 |
| Supplemental HS | Reacts violently with water. |
| Precautionary Statements | P222-P223-P231 + P232-P280-P370 + P378-P422 |
| Hazard Codes | F:Flammable;C:Corrosive; |
| Risk Phrases | R11;R14;R34;R48/20;R63;R65;R67 |
| Safety Phrases | S26-S36/37/39-S45-S61-S62-S6A-S46-S43A-S16-S27 |
| RIDADR | UN 3394 4.2/PG 1 |
| WGK Germany | 2 |
| RTECS | BD2203500 |
| Packaging Group | I |
| Hazard Class | 4.3 |
| HS Code | 2931900090 |
Customs
| HS Code | 2931900090 |
|---|---|
| Summary | 2931900090. other organo-inorganic compounds. VAT:17.0%. Tax rebate rate:13.0%. Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward). MFN tariff:6.5%. General tariff:30.0% |
Articles3
More Articles| Insertion, elimination and isomerisation of olefins at alkylaluminium hydride: an experimental and theoretical study. Dalton Trans. 44 , 15286-96, (2015) The insertion, elimination and isomerisation of octenes with di-n-octylaluminium hydride [HAl(Oct)2], tri-n-octylaluminium [Al(Oct)3] and sec-octylaluminium species have been studied as individual ste... | |
| Broadening of polymer chromatographic signals: Analysis, quantification and correction through effective diffusion coefficients. J. Chromatogr. A. 1407 , 193-202, (2015) Average molecular weights and polydispersity indexes are some of the most important parameters considered in the polymer characterization. Usually, gel permeation chromatography (GPC) and multi angle ... | |
| The promoting effects of alginate oligosaccharides on root development in Oryza sativa L. mediated by auxin signaling. Carbohydr. Polym. 113 , 446-54, (2014) Alginate oligosaccharides (AOS), which are marine oligosaccharides, are involved in regulating plant root growth, but the promotion mechanism for AOS remains unclear. Here, AOS (10-80 mg/L) induced th... |
Synonyms
| tri-isobutyl aluminium |
| Al(isobutyl)3 |
| Tris(2-methylpropyl)aluminum |
| tri-i-butylaluminium |
| Aluminium, tri-isobutyl- |
| ALUMINUM TRIISOBUTYL |
| MFCD00008929 |
| Aluminum, triisobutyl- |
| tibal |
| Aluminum, tris(2-methylpropyl)- |
| triisobutyl-aluminu |
| Triisobutylaluminum |
| Tris(isobutyl)aluminum |
| triisobutyl-alane |
| tiba solution |
| TRI-I-BUTYLALUMINUM |
| TriisobutylAmmonium |
| 1Y1&1-AL-1Y1&1&1Y1&1 |
| Triisobutylaluminium |
| tris(isobutyl)alane |
| EINECS 202-906-3 |
