CAS 667-27-6|ethylbrom(difluor)acetat

Introduction:Basic information about CAS 667-27-6|ethylbrom(difluor)acetat, including its chemical name, molecular formula, synonyms, physicochemical properties, and safety information, etc.
Common Nameethylbrom(difluor)acetat
CAS Number667-27-6Molecular Weight202.982
Density1.7±0.1 g/cm3Boiling Point114.7±35.0 °C at 760 mmHg
Molecular FormulaC4H5BrF2O2Melting Point/
MSDSChineseUSAFlash Point23.2±25.9 °C
Symbol
GHS02, GHS05
Signal WordDanger

Names

NameEthyl Bromodifluoroacetate
SynonymMore Synonyms

Chemical & Physical Properties

Density1.7±0.1 g/cm3
Boiling Point114.7±35.0 °C at 760 mmHg
Molecular FormulaC4H5BrF2O2
Molecular Weight202.982
Flash Point23.2±25.9 °C
Exact Mass201.944092
PSA26.30000
LogP2.02
Vapour Pressure19.7±0.2 mmHg at 25°C
Index of Refraction1.412
InChIKeyIRSJDVYTJUCXRV-UHFFFAOYSA-N
SMILESCCOC(=O)C(F)(F)Br
Storage conditionFlammables area

Safety Information

Symbol
GHS02, GHS05
Signal WordDanger
Hazard StatementsH225-H314
Precautionary StatementsP210-P280-P305 + P351 + P338-P310
Personal Protective EquipmentFaceshields;full-face respirator (US);Gloves;Goggles;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter
Hazard CodesC:Corrosive
Risk PhrasesR10;R34
Safety PhrasesS26-S36/37/39-S45-S16
RIDADRUN 2924 3/PG 2
WGK Germany3
Packaging GroupII
Hazard Class3
HS Code2942000000

Customs

HS Code2915900090
Summary2915900090 other saturated acyclic monocarboxylic acids and their anhydrides, halides, peroxides and peroxyacids; their halogenated, sulphonated, nitrated or nitrosated derivatives VAT:17.0% Tax rebate rate:9.0% Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward) MFN tariff:5.5% General tariff:30.0%

Articles4

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Synthesis of 4-substituted 3,3-difluoropiperidines.

J. Org. Chem. 75(3) , 929-32, (2010)

Synthetic strategies toward 4-substituted 3,3-difluoropiperidines were evaluated. 4-Alkoxymethyl- and 4-aryloxymethyl-3,3-difluoropiperidines were synthesized via 1,4-addition of ethyl bromodifluoroac...

Visible-light-mediated fluoroalkylation of isocyanides with ethyl bromofluoroacetates: unified synthesis of mono- and difluoromethylated phenanthridine derivatives.

Org. Lett. 16(11) , 2938-41, (2014)

A practical and unified strategy has been described for the preparation of mono- and difluoromethylated phenanthridine derivatives using a visible-light-promoted alkylation and decarboxylation sequenc...

Enantioselective synthesis of α,α-difluoro-β-lactams using amino alcohol ligands.

Org. Biomol. Chem. 12(33) , 6484-9, (2014)

A practical and highly enantioselective Reformatsky reaction of ethyl bromodifluoroacetate with imines using a cheap and commercially available amino alcohol ligand is described. A variety of α,α-difl...

Synonyms

MFCD00042069
Acetic acid, bromodifluoro-, ethyl ester
EINECS 211-567-0
ethyl 2-bromo-2,2-difluoroacetate
ethylbrom(difluor)acetat
Ethyl bromodifluoroacetate
Ethyl bromo(difluoro)acetate
Acetic acid, 2-bromo-2,2-difluoro-, ethyl ester
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