(+)-(8,8-Dichlorocamphorylsulfonyl)oxaziridine CAS 127184-05-8

Introduction：Basic information about (+)-(8,8-Dichlorocamphorylsulfonyl)oxaziridine CAS 127184-05-8, including its chemical name, molecular formula, synonyms, physicochemical properties, and safety information, etc.

(+)-(8,8-Dichlorocamphorylsulfonyl)oxaziridine Basic information

• Product Name: (+)-(8,8-Dichlorocamphorylsulfonyl)oxaziridine
• Synonyms: (+)-3,3-DICHLORO-2,N-EPOXY-EXO-10,2-BORNANESULTAM;4H-4a,7-Methanooxazirino3,2-i2,1benzisothiazole, 8,8-dichlorotetrahydro-9,9-dimethyl-, 3,3-dioxide, (2R,4aS,7S,8aR)-;(+)-[(8,8-DICHLOROCAMPHORYL)-SULFONYL]-OXAZIRIDINE 97+%;[2R-(2α,4aα,7α,8aR*)]-8,8-Dichlorotetrahydro-9,9-diMethyl-4H-4a,7-Methanooxazirino[3,2-i][2,1]benzisothiazole 3,3-Dioxide;(+)-(8,8-DichlorocaMphorylsulfonyl)oxaziridine >=97.0% (T);(4aS,7S,8aR)-8,8-dichloro-9,9-dimethyltetrahydro-4H-4a,7-methanobenzo[c][1,2]oxazireno[2,3-b]isothiazole 3,3-dioxide;(1S,6R,8S)-7,7-dichloro-11,11-dimethyl-5-oxa-3λ?-thia-4-azatetracyclo[6.2.1.01,?.0?,?]undecane-3,3-dione;8AR)-8
• CAS: 127184-05-8
• MF: C10H13Cl2NO3S
• MW: 298.19
• Product Categories: Heterocycles;Miscellaneous Reagents
• Mol File: 127184-05-8.mol

(+)-(8,8-Dichlorocamphorylsulfonyl)oxaziridine Chemical Properties

• Melting point: 181-186 °C
• Boiling point: 390.5±52.0 °C(Predicted)
• density: 1.68±0.1 g/cm3(Predicted)
• storage temp.: 2-8°C
• solubility: Chloroform (Slightly), DMSO (Slightly), Methanol (Slightly)
• pka: -15.63±0.60(Predicted)
• form: Solid
• color: White to Off-White
• Optical Rotation: [α]20/D +89±3°, c = 0.5% in chloroform
• BRN: 3653352
• InChI: InChI=1/C10H13Cl2NO3S/c1-7(2)6-3-4-8(7)5-17(14,15)13-10(8,16-13)9(6,11)12/h6H,3-5H2,1-2H3/t6-,8-,10+,13?/s3
• InChIKey: HAMBQYFZDBYWHU-XCDSEQPNNA-N
• SMILES: [C@@]123ON1S(=O)(=O)C[C@@]12CC[C@@]([H])(C1(C)C)C3(Cl)Cl |&1:0,7,10,r|

Safety Information

• Safety Statements: 22-24/25
• RIDADR: 1479
• WGK Germany: 3
• F: 8-10
• HazardClass: 5.1
• PackingGroup: III
• Storage Class: 11 - Combustible Solids

(+)-(8,8-Dichlorocamphorylsulfonyl)oxaziridine Usage And Synthesis

Chemical Properties

White Solid

Uses

Chiral oxidizing agent.

Purification Methods

Recrystallise the enantiomers from EtOH [Davis & Weismiller J Org Chem 55 3715 1990].

(+)-(8,8-Dichlorocamphorylsulfonyl)oxaziridine Preparation Products And Raw materials

• Raw materials: (3aS,6S)-7,7-Dichloro-4,5,6,7-tetrahydro-8,8-diMethyl-3H-3a,6-Methano-2,1-benzisothiazole 2,2-Dioxide-->(1S)-(-)-CAMPHORSULFONYLIMINE