Introduction：Basic information about 1-Adamantanecarbonyl chloride CAS 2094-72-6, including its chemical name, molecular formula, synonyms, physicochemical properties, and safety information, etc.
1-Adamantanecarbonyl chloride Basic information
| Product Name: | 1-Adamantanecarbonyl chloride |
| Synonyms: | 1-ADAMANTANECARBONYL CHLORIDE;1-ADAMANTANECARBOXYLIC ACID CHLORIDE;1-ADAMANTANECARBOXYLIC ACID CHLOROANHYDRIDE;ADAMANTANE-1-CARBONYL CHLORIDE;AKOS BC-0659;TRICYCLO[3.3.1.1]DECANE-1-CARBOXYLIC ACID CHLORIDE;1-Adamantanecarbony chloride;38.1-adamantanecarbonyl chloride |
| CAS: | 2094-72-6 |
| MF: | C11H15ClO |
| MW: | 198.69 |
| EINECS: | 218-252-7 |
| Product Categories: | Adamantane derivatives;Adamantanes;Acid Halides;Carbonyl Compounds;Organic Building Blocks |
| Mol File: | 2094-72-6.mol |
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1-Adamantanecarbonyl chloride Chemical Properties
| Melting point | 49-51 °C(lit.) |
| Boiling point | 135-136 °C10 mm Hg(lit.) |
| density | 1.0490 (rough estimate) |
| refractive index | 1.5364 (estimate) |
| Fp | >230 °F |
| storage temp. | Inert atmosphere,2-8°C |
| solubility | soluble in Toluene |
| form | Crystalline Solid |
| color | White to almost white |
| Water Solubility | may decompose |
| Sensitive | Moisture Sensitive |
| BRN | 389960 |
| InChI | 1S/C11H15ClO/c12-10(13)11-4-7-1-8(5-11)3-9(2-7)6-11/h7-9H,1-6H2/t7-,8+,9-,11- |
| InChIKey | MIBQYWIOHFTKHD-KJZNFTALSA-N |
| SMILES | ClC(=O)C12C[C@H]3C[C@H](C[C@H](C3)C1)C2 |
| CAS DataBase Reference | 2094-72-6(CAS DataBase Reference) |
| NIST Chemistry Reference | 1-Adamantanecarboxlic acid chloride(2094-72-6) |
Safety Information
| Hazard Codes | C |
| Risk Statements | 14-34-37 |
| Safety Statements | 26-36/37/39-45-24/25 |
| RIDADR | UN 3261 8/PG 2 |
| WGK Germany | 3 |
| F | 10-21 |
| HazardClass | 8 |
| PackingGroup | III |
| HS Code | 29162090 |
| Storage Class | 8A - Combustible corrosive hazardous materials |
| Hazard Classifications | Skin Corr. 1B |
1-Adamantanecarbonyl chloride Usage And Synthesis
| Chemical Properties | White to almost white crystalline solid |
| Uses | 1-Adamantanecarbonyl chloride was used in the preparation of efficient amine-modified oligodeoxynucleotides for fabrication of DNA microarrays. |
| General Description | 1-Adamantanecarbonyl chloride on reaction with triethylammonium isopropylphosphite forms mixed anhydride, an efficient capping reagent for the hydrogen-phosphonate DNA synthesis. It is a good substrate for Friedel–Crafts acylation of anisole in the presence of indium metal. |
1-Adamantanecarbonyl chloride Preparation Products And Raw materials
| Raw materials | Dichloromethane-->Thionyl chloride-->1-Adamantanecarboxylic acid |
| Preparation Products | 2-(1-Adamantyl)propan-2-ol-->1-ADAMANTYL ISOTHIOCYANATE-->1-(1-ADAMANTYL)PROPAN-1-OL-->Ethyl adamantane-1-carboxylate-->1-ADAMANTANECARBOXAMIDE-->ADAMANTANE-1-CARBOXYLIC ACID METHYL ESTER-->3-[(1-ADAMANTYLCARBONYL)AMINO]PROPANOIC ACID-->1-ADAMANTYL(PHENYL)METHANONE |
