AdBrettPhos Pd G3 CAS 1445972-29-1
Introduction：Basic information about AdBrettPhos Pd G3 CAS 1445972-29-1, including its chemical name, molecular formula, synonyms, physicochemical properties, and safety information, etc.
AdBrettPhos Pd G3 Basic informationReaction
| Product Name: | AdBrettPhos Pd G3 |
| Synonyms: | Methanesulfonato[2-(di-1-adamantylphosphino)-3,6-dimethoxy-2',4',6'-tri-i-propyl-1,1'-biphenyl](2'-amino-1,1'-biphenyl-2-yl)palladium(II), AdBrettPhos Palladacycle Gen. 3;METHANESULFONATO[2-(DI-1-ADAMANTYLPHOSPHINO)-3,6-DIMETHOXY-2',4',6'-TRI-I-PROPYL-1,1'-BIPHENYL](2'-AMINO-1,1'-BIPHENYL-2-YL)PALLADIUM(II),MIN.98%[ADBRETTPHOSPALLADACYCLEGEN.3];Methanesulfonato[2-(di-1-adamantylphosphino)-3,6-dimethoxy-2',4',6'-tri-i-propyl-1,1'-biphenyl](2'-amino-1,1'-biphenyl-2-yl)palladium(II);AdBrettPhos Palladacycle Gen. 3;bis(adamantan-1-yl)[3,6-dimethoxy-2',4',6'-tris(pro pan-2-yl)-[1,1'-biphenyl]-2-yl]phosphane;Methanesulfonato[2-(di-1-adamantylphosphino)-3,6-dimethoxy-2...;AdBrettPhos Pd G3;bis(1-adamantyl)-[3,6-dimethoxy-2-(2,4,6-triisopropylphenyl)phenyl]phosphane |
| CAS: | 1445972-29-1 |
| MF: | C56H74NO5PPdS |
| MW: | 1010.66 |
| EINECS: | |
| Product Categories: | |
| Mol File: | 1445972-29-1.mol |
AdBrettPhos Pd G3 Chemical Properties
| Melting point | 251-253 °C |
| storage temp. | 2-8°C, protect from light, stored under nitrogen |
| form | solid |
| color | brown to green |
| InChIKey | OZFYYHNERORONM-UHFFFAOYSA-M |
Safety Information
| WGK Germany | WGK 3 |
| Storage Class | 11 - Combustible Solids |
| Reaction | Palladium catalyst used in the highly selective monoarylation of ammonia. |
| Uses | Buchwald 3rd Generation Pd Precatalyst adorned by the bulk di-adamntyl BrettPhos ligand. This complex has been used in the monoarylation of ammonia, displaying apptitude for otherwise difficult 5-member heterocyclic substrates. Mild and Highly Selective Palladium-Catalyzed Monoarylation of Ammonia Enabled by the Use of Bulky Biarylphosphine Ligands and Palladacycle Precatalysts |
| reaction suitability | reaction type: Buchwald-Hartwig Cross Coupling Reaction reaction type: Cross Couplings reaction type: Heck Reaction reaction type: Hiyama Coupling reaction type: Negishi Coupling reaction type: Sonogashira Coupling reaction type: Stille Coupling reaction type: Suzuki-Miyaura Coupling reagent type: catalyst |
AdBrettPhos Pd G3 Preparation Products And Raw materials
