alpha-Amylcinnamaldehyde CAS 122-40-7

Introduction:Basic information about alpha-Amylcinnamaldehyde CAS 122-40-7, including its chemical name, molecular formula, synonyms, physicochemical properties, and safety information, etc.

alpha-Amylcinnamaldehyde Basic information

Product Name:alpha-Amylcinnamaldehyde
Synonyms:2-Benzylidenheptanal;AMYLZIMTALDEHYD ALPHA-;A-AMYL CINNAMIC ALDEHYDE;2-PENTYL-3-PHENYLPROPENOIC ALDEHYDE;2-benzylidene heptanal;2-(Phenylmethylene)-heptanal;ALPHA-PENTYLCINNAMALDEHYDE;ALPHA-N-AMYLCINNAMALDEHYDE
CAS:122-40-7
MF:C14H18O
MW:202.29
EINECS:204-541-5
Product Categories:A-B;Alphabetical Listings;Flavors and Fragrances;Aldehydes;C10 to C21;Carbonyl Compounds;Pharmaceutical Intermediates;11
Mol File:122-40-7.mol

alpha-Amylcinnamaldehyde Chemical Properties

Melting point 80°C
Boiling point 287-290 °C(lit.)
density 0.97 g/mL at 25 °C(lit.)
vapor pressure 0.133Pa at 25℃
refractive index n20/D 1.557(lit.)
FEMA 2061 | ALPHA-AMYLCINNAMALDEHYDE
Fp >230 °F
storage temp. 2-8°C
solubility Soluble in alcohol and perfume materials. Insoluble in water.
form liquid
color Pale-yellow oil or liquid
Odorfloral jasmine odor
Odor Typefloral
biological sourcesynthetic
Water Solubility 181.69mg/L at 25℃
JECFA Number685
Major Applicationflavors and fragrances
Cosmetics Ingredients FunctionsPERFUMING
InChI1S/C14H18O/c1-2-3-5-10-14(12-15)11-13-8-6-4-7-9-13/h4,6-9,11-12H,2-3,5,10H2,1H3/b14-11+
InChIKeyHMKKIXGYKWDQSV-SDNWHVSQSA-N
SMILES[H]C(/C(CCCCC)=C/C1=CC=CC=C1)=O
LogP2.498 at 25℃
CAS DataBase Reference122-40-7(CAS DataBase Reference)
NIST Chemistry ReferenceHeptanal, 2-(phenylmethylene)-(122-40-7)
EPA Substance Registry System2-(Phenylmethylene)heptanal (122-40-7)

Safety Information

Hazard Codes Xi,N
Risk Statements 36/37/38-51/53-43
Safety Statements 26-37/39-61-36/37
RIDADR UN 3082 9 / PGIII
WGK Germany 2
RTECS GD6825000
TSCA TSCA listed
HazardClass 9
PackingGroup III
HS Code 29122990
Storage Class10 - Combustible liquids
Hazard ClassificationsAquatic Chronic 2
Skin Sens. 1
Hazardous Substances Data122-40-7(Hazardous Substances Data)
ToxicityLD50 orl-rat: 3730 mg/kg FCTXAV 2,327,64

alpha-Amylcinnamaldehyde Usage And Synthesis

DescriptionAmylcinnamic aldehyde is an oxidation product ofamylcinnamic alcohol, one component of the "fragrancemix" and can be found as a sensitizer in casesof contact dermatitis in bakers.
Chemical PropertiesLight yellow transparent liquid
Chemical Propertiesalpha-Amylcinnamaldehyde has been identifiedas an aroma volatile of black tea. It is a light yellow liquid with a floral, slightlyfatty odor, which becomes reminiscent of jasmine when diluted.The aldehyde isrelatively unstable and must be stabilized by antioxidants.
It is prepared from benzaldehyde and heptanal in the same way as cinnamaldehyde.
??-Amylcinnamaldehyde is a very popular fragrance substance for creating jasminenotes. It is stable to alkali and long-lasting; large quantities are used, particularlyin soap perfumes.
Chemical Propertiesα-Amylcinnamaldehyde has a distinct floral (jasmine, lily) note.
OccurrenceReported found in black tea and soybean
Usesamyl cinnamal is used as a fragrance. Although it is naturally occurring in some plants, it is most often synthetically derived when used in cosmetic products.
UsesAmylcinnamaldehyde is a flavoring agent that is a yellow liquid with an odor similar to jasmine. It is insoluble in glycerin and propylene, soluble in fixed oils and mineral oil. It is obtained by chemical synthesis. It can be used alone or in combination with other flavoring substances or adjuvants. It is also termed amylcinnomaldehyde.
UsesRaw material in the production of perfumes; some perfumery uses (tuberose; peach; cherry; Estee; honeysuckle Chevrefeuille)Cross: amylcinnamic alcohol. AMYL CINNAMAL
PreparationBy condensation of n-amyl aldehyde with cinnamic aldehyde. This method of condensation of aromatic aldehydes withaliphatic aldehydes has the maximum yield in α-amylcinnamic aldehyde with little formation of the inferior homologs. The methyl,ethyl and propyl amylcinnamic aldehyde analogs exhibit a characteristic scent.
DefinitionChEBI: Alpha-Amylcinnamaldehyde is a member of cinnamaldehydes.
Taste threshold valuesTaste characteristics at 40 ppm: sweet, floral, spice-like with cinnamic and waxy nuance
General DescriptionThe short-term feeding studies in rats was carried out using α-amylcinnamaldehyde, a flavouring matter.
Flammability and ExplosibilityNot classified
Contact allergensa-Amyl-cinnamic aldehyde is an oxidation product ofamylcinnamic alcohol, a sensitizing fragrance, and onecomponent of the “fragrance mix.” It can also be a sensitizerin bakers. It has to be mentioned by name incosmetics within the EU.
Safety ProfileModerately toxic byingestion. A severe skin irritant. See alsoALDEHYDES. When heated todecomposition it emits acrid smoke andirritating fumes.
MetabolismSo far as is known, all aromatic aldehydes are metabolized in the animal body by oxidation to the corresponding acids. In some instances, the aldehydes are excreted as glucuronides. Cinnamic aldehyde is oxidized to cinnamic acid which is then degraded to benzoic acid, but ethyl cinnamic aldehyde is oxidized to the corresponding acid and is not further metabolized(Williams, 1959).

alpha-Amylcinnamaldehyde Preparation Products And Raw materials

Raw materialsSodium chloride-->Benzaldehyde-->Castor oil-->Potassium hydroxide solution-->Diphenylamine-->Heptaldehyde-->trans-Cinnamic acid-->ISOAMYL ALCOHOL
Preparation Productsalpha-Hexylcinnamaldehyde
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