Basic Green 1 CAS 633-03-4
Introduction：Basic information about Basic Green 1 CAS 633-03-4, including its chemical name, molecular formula, synonyms, physicochemical properties, and safety information, etc.
Basic Green 1 Basic information
| Product Name: | Basic Green 1 |
| Synonyms: | brilliantgreencrystalsh;brilliantgreendsc;brilliantgreeng;brilliantgreengx;brilliantgreenlake;brilliantgreenp;brilliantgreenspecial;ANILINE GREEN |
| CAS: | 633-03-4 |
| MF: | C27H34N2O4S |
| MW: | 482.63 |
| EINECS: | 211-190-1 |
| Product Categories: | Analytical Chemistry;Ion Association;Stains and Dyes;Dyes and Pigments;AR;Triphenylmethane |
| Mol File: | 633-03-4.mol |
Basic Green 1 Chemical Properties
| Melting point | 210 °C (dec.)(lit.) |
| Boiling point | 100.0 |
| density | 1.1016 (rough estimate) |
| bulk density | 500-600kg/m3 |
| vapor density | 16.6 (vs air) |
| vapor pressure | 0Pa at 25℃ |
| refractive index | 1.6510 (estimate) |
| storage temp. | room temp |
| solubility | 100g/l |
| form | Powder/Solid |
| Colour Index | 42040 |
| color | Metallic green |
| PH Range | Yellow (0.0) to green (2.6) |
| PH | 2.5 (10g/l, H2O, 25℃) |
| Odor | Odorless |
| Water Solubility | 100 G/L (25 ºC) |
| λmax | 625nm, 428nm |
| Merck | 14,1374 |
| BRN | 3901207 |
| Stability: | Stable. Incompatible with strong oxidizing agents, reducing agents. |
| Biological Applications | Antimalarial agent; detecting carious tissue; treating anococcygeal pain syn- drome; wound dressing materials; catheter; mouthwash |
| Major Application | Black matrix, color filter, photoresists, sensors, inks, rodenticide, dyes, cosmetics, detecting dental carious tissue, Escherichia coli, antimalarial agent, dressing material, treatment of cancer, medical devices |
| Cosmetics Ingredients Functions | HAIR DYEING |
| InChI | 1S/C27H33N2.H2O4S/c1-5-28(6-2)25-18-14-23(15-19-25)27(22-12-10-9-11-13-22)24-16-20-26(21-17-24)29(7-3)8-4;1-5(2,3)4/h9-21H,5-8H2,1-4H3;(H2,1,2,3,4)/q+1;/p-1 |
| InChIKey | UURSSPGMJADCAU-UHFFFAOYSA-N |
| SMILES | OS([O-])(=O)=O.CCN(CC)c1ccc(cc1)C(\c2ccccc2)=C3/C=CC(\C=C3)=[N+](/CC)CC |
| LogP | 0.765 at 20℃ |
| CAS DataBase Reference | 633-03-4(CAS DataBase Reference) |
| EPA Substance Registry System | C.I. Basic Green 1 (633-03-4) |
Safety Information
| Hazard Codes | Xn |
| Risk Statements | 22-36-36/37/38-20/21/22 |
| Safety Statements | 26-39-36-24/25 |
| RIDADR | 2811 |
| WGK Germany | 3 |
| RTECS | BP6825000 |
| F | 10-21 |
| TSCA | TSCA listed |
| HS Code | 3204 13 00 |
| HazardClass | 6.1(a) |
| PackingGroup | II |
| Storage Class | 11 - Combustible Solids |
| Hazard Classifications | Acute Tox. 4 Oral Aquatic Acute 1 Aquatic Chronic 1 Eye Dam. 1 Skin Irrit. 2 Skin Sens. 1 |
| Hazardous Substances Data | 633-03-4(Hazardous Substances Data) |
| Toxicity | LD100 i.v. in mice: 3 mg/kg (Anderson) |
| Description | C.I. Basic Green 1 is a metallic green, odorlesscrystal or powder. Molecular weight =482.69; Meltingpoint =210℃. Soluble in water. | ||||||||||||||||||||||||||||||
| Chemical Properties | metallic green crystals | ||||||||||||||||||||||||||||||
| Chemical Properties | C.I. Basic Green 1 is a metallic green, odorless crystal or powder | ||||||||||||||||||||||||||||||
| Uses | Dyeing silk, wool, leather, jute and cotton yellowish-green; manufacture of green ink; biological stain; indicator. | ||||||||||||||||||||||||||||||
| Uses | Brilliant Green a stain used in bacteriological media. | ||||||||||||||||||||||||||||||
| Preparation | in the presence of sulfuric acid hydrochloric acid or, Benzaldehyde?and N,N-diethylbenzenamine condensation, and then will product oxidation, and translated into sulfate. The first generation of resin mixture will suddenly for curing crystalline good crystals. | ||||||||||||||||||||||||||||||
| Definition | ChEBI: An organic hydrogensulfate salt having 4-{[4-(diethylamino)phenyl](phenyl)methylidene}-N,N-diethylcyclohexa-2,5-dien-1-iminium as the counterion. | ||||||||||||||||||||||||||||||
| General Description | Brilliant green is a triphenylmethane dye, found to be toxic to humans and animals. It is widely used in dying wool, leather, silk, jute, and cotton. It is also used in the manufacturing of green ink, as a staining constituent of bacteriological media. | ||||||||||||||||||||||||||||||
| Flammability and Explosibility | Non flammable | ||||||||||||||||||||||||||||||
| Biochem/physiol Actions | Brilliant Green is a dye and an antiseptic agent. | ||||||||||||||||||||||||||||||
| Safety Profile | Poison by ingestion,intraperitoneal, and intravenous routes. Armld human skin irritant. Mutation datareported. See also ALDEHYDES andSULFATES. When heated todecomposition it emits very toxic fumes ofNOx, NH3, and SOx. | ||||||||||||||||||||||||||||||
| Potential Exposure | C.I. Basic Green 1 is used in dyeing silk, wool, leather, jute, and cotton yellowish-green; manufacturing green ink; as staining constituent of bacteriological media; indicator, an intestinal anthelmintic; a C.I. Basic Green 1 861 wound antiseptic; treatment of mycotic infections; agricultural fungicide (Not registered as a pesticide in the United States). | ||||||||||||||||||||||||||||||
| First aid | If this chemical gets into the eyes, remove anycontact lenses at once and irrigate immediately for atleast 15 min, occasionally lifting upper and lower lids.Seek medical attention immediately. If this chemical contacts the skin, remove contaminated clothing and washimmediately with soap and water. Seek medical attentionimmediately. If this chemical has been inhaled, removefrom exposure, begin rescue breathing (using universalprecautions, including resuscitation mask) if breathing hasstopped and CPR if heart action has stopped. Transferpromptly to a medical facility. When this chemical hasbeen swallowed, get medical attention. Give large quantities of water and induce vomiting. Do not make anunconscious person vomit. | ||||||||||||||||||||||||||||||
| storage | Color Code—Blue: Health Hazard/Poison: Storein a secure poison location | ||||||||||||||||||||||||||||||
| Shipping | UN3143 Dyes, solid, toxic, n.o.s. or Dye intermediates, solid, toxic, n.o.s., Hazard Class: 6.1; Labels: 6.1-Poisonous materials, Technical Name Required. UN2811 Toxic solids, organic, n.o.s., Hazard Class: 6.1; Labels: 6.1-Poisonous materials, Technical Name Required. | ||||||||||||||||||||||||||||||
| Purification Methods | Purify the dye by precipitating the perchlorate from aqueous solution (0.3%) after filtering, heating to 75o and adjusting to pH 1-2. Recrystallise it from EtOH/water (1:4) [Kerr & Gregory Analyst (London) 94 1036 1969]. [Beilstein 13 IV 2281.] | ||||||||||||||||||||||||||||||
| Properties and Applications | bright green. Green flash golden sand shape. Slightly soluble in cold water, in 98 ℃ of hot water dissolves only 8 g/L, soluble in ethanol to blue. The strong sulfuric acid for yellow green, diluted into blue; For orange in nitric acid. The dye solution for blue purple, add sodium hydroxide have dark purple precipitation; Join the hydrochloric acid become green light yellow. Used for silk, wool, acrylic, tannin mordant dyeing cotton cloth dyeing. Also used in leather, hemp, paper, wood, bamboo or color, also used in the manufacture of paint, medicine used for disinfectant.
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| Incompatibilities | Oxidizing agents, reducing agents; anionics, and aqueous solutions of bentonite. Keep away from moisture | ||||||||||||||||||||||||||||||
Basic Green 1 Preparation Products And Raw materials
| Raw materials | Lead dioxide-->Benzaldehyde-->N,N-Diethylaniline |
