Introduction：Basic information about BENZYLMAGNESIUM BROMIDE CAS 1589-82-8, including its chemical name, molecular formula, synonyms, physicochemical properties, and safety information, etc.
BENZYLMAGNESIUM BROMIDE Basic information
| Product Name: | BENZYLMAGNESIUM BROMIDE |
| Synonyms: | benzylbromomagnesium;Benzylmagnesium Bromide (19% in Tetrahydrofuran, ca. 1mol/L);BENZYLMAGNESIUM BROMIDE;Bromo(phenylmethyl)magnesium;Bromobenzylmagnesium;magnesium methanidylbenzene bromide;Benzylmagnesium Bromide (ca. 12% in Tetrahydrofuran, ca. 0.6mol/L);BenzylMagnesiuM BroMide 1M in Tetrahydrofuran |
| CAS: | 1589-82-8 |
| MF: | C7H7BrMg |
| MW: | 195.34 |
| EINECS: | 216-459-7 |
| Product Categories: | Grignard Reagent;Classes of Metal Compounds;Grignard Reagents;Grignard Reagents & Alkyl Metals;Mg (Magnesium) Compounds;Synthetic Organic Chemistry;Typical Metal Compounds |
| Mol File: | 1589-82-8.mol |
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BENZYLMAGNESIUM BROMIDE Chemical Properties
| InChI | InChI=1S/C7H7.BrH.Mg/c1-7-5-3-2-4-6-7;;/h2-6H,1H2;1H;/q;;+1/p-1 |
| InChIKey | UHPSYHZSDNXIHK-UHFFFAOYSA-M |
| SMILES | C(C1C=CC=CC=1)[Mg]Br |
| CAS DataBase Reference | 1589-82-8 |
Safety Information
| RIDADR | 2924 |
| HazardClass | 3/8 |
| PackingGroup | II |
| HS Code | 29319090 |
BENZYLMAGNESIUM BROMIDE Usage And Synthesis
| Uses | Benzylmagnesium Bromide is mainly used for the formation of diastereomeric o-toluylmethanol via a format reaction. Moreover, benzylmagnesium bromide only generates o-tolylmethanol when used in excess or at higher temperatures[1]. |
| storage | Store under inert gas |
| References | [1] MARO\VS BELLA. Reaction of selected carbohydrate aldehydes with benzylmagnesium halides: benzyl versus o-tolyl rearrangement.[J]. Beilstein Journal of Organic Chemistry, 2014: 1942-1950. DOI:10.3762/bjoc.10.202. |
BENZYLMAGNESIUM BROMIDE Preparation Products And Raw materials
| Preparation Products | 1-Phenylnonane-->3-PHENYL-1,1,1-TRIFLUOROPROPAN-2-ONE-->NEOPENTYLBENZENE-->4-Benzyl-2,6-dichloropyrimidine |
