Bismuth(III) trifluoromethanesulfonate CAS 88189-03-1

Introduction：Basic information about Bismuth(III) trifluoromethanesulfonate CAS 88189-03-1, including its chemical name, molecular formula, synonyms, physicochemical properties, and safety information, etc.

Bismuth(III) trifluoromethanesulfonate Basic information

• Product Name: Bismuth(III) trifluoromethanesulfonate
• Synonyms: BISMUTH(III)TRIFLATE;BISMUTH(III) TRIFLUOROMETHANESULFONATE;BISMUTH(III)TRIFLUOROMETHANESULPHONATE;BISMUTH TRIFLATE;BISMUTH TRIFLUOROMETHANESULFONATE HYDRATE;BISMUTH TRIFLUOROMETHANESULFONATE, ANHY&;Trifluoromethanesulfonicacidbismuthsalt;Bismuth(III)trifluoromethanesulfonate,min.98%(Bismuthtriflate)
• CAS: 88189-03-1
• MF: 3CF3O3S.Bi
• MW: 656.18
• Product Categories: metal triflate compound;triflate;Bismuth;Catalysis and Inorganic Chemistry;Chemical Synthesis
• Mol File: 88189-03-1.mol

Bismuth(III) trifluoromethanesulfonate Chemical Properties

• Melting point: 300 °C
• storage temp.: Inert atmosphere,Room Temperature
• solubility: Soluble in organics acetonitrile, dioxane, dimethyl formamide and dimethyl sulfoxide.
• form: Liquid
• color: Clear colorless
• Hydrolytic Sensitivity: 5: forms reversible hydrate
• Sensitive: Hygroscopic
• Stability: hygroscopic
• InChI: InChI=1S/3CHF3O3S.Bi/c3*2-1(3,4)8(5,6)7;/h3*(H,5,6,7);/q;;;+3/p-3
• InChIKey: HIYUMYXSGIKHHE-UHFFFAOYSA-M
• SMILES: C(F)(S([O-])(=O)=O)(F)F.C(F)(F)(F)S([O-])(=O)=O.C(F)(F)(F)S([O-])(=O)=O.[Bi+3]

Safety Information

• Hazard Codes: Xi
• Risk Statements: 36/37/38
• Safety Statements: 26-24/25
• WGK Germany: 3
• Hazard Note: Irritant
• TSCA: No
• HazardClass: 8
• HS Code: 29049090
• Storage Class: 11 - Combustible Solids

Bismuth(III) trifluoromethanesulfonate Usage And Synthesis

Uses

Bismuth(III) trifluoromethanesulfonate is powerful Lewis acid useful in a number of catalytic reactions. 

Chemical Properties

White powder

Uses

Catalyst for organic syntheses.

Uses

Bismuth(III) trifluoromethanesulfonate acts as a catalyst in Friedel-Crafts acylation and cycloisomerization of allene-enol ethers. It behaves as a direct substitution catalyst and involved in the substitution of allylic, propargylic, and benzylic alcohols with sulfonamides, carboxamides and carbamates. Further, it is also used in Mukaiyama aldol reactions.

Uses

Catalyzes direct substitution of allylic, propargylic, and benzylic alcohols with sulfonamides, carbamates, and carboxamides.

reaction suitability

core: bismuth
reagent type: catalyst