Cyhexatin CAS 13121-70-5

Introduction:Basic information about Cyhexatin CAS 13121-70-5, including its chemical name, molecular formula, synonyms, physicochemical properties, and safety information, etc.

Cyhexatin Basic information

Product Name:Cyhexatin
Synonyms:PLICTRAN;PLICTRAN(R);MITACID;TRICYCLOHEXYLTIN HYDROXIDE;TRICYCLOHEXYLTIN(IV) HYDROXIDE;TRICYCLOHEXYLHYDROXYTIN;dowco-213;ent27,395-x
CAS:13121-70-5
MF:C18H34OSn
MW:385.17
EINECS:236-049-1
Product Categories:AcaricidesPesticides&Metabolites;Alpha sort;C;CAlphabetic;CO - CZ;Pesticides;Pesticides&Metabolites
Mol File:13121-70-5.mol

Cyhexatin Chemical Properties

Melting point 195-198°C
Boiling point 426.1±28.0 °C(Predicted)
vapor pressure 3×10-7 Pa (20 °C)
Fp >100 °C
storage temp. 0-6°C
solubility Chloroform (Slightly, Heated, Sonicated)
Water Solubility <1 mg l-1(25 °C)
form solid
pka6.76±0.70(Predicted)
Hydrolytic Sensitivity4: no reaction with water under neutral conditions
Merck 13,2789
CAS DataBase Reference13121-70-5(CAS DataBase Reference)
EPA Substance Registry SystemCyhexatin (13121-70-5)

Safety Information

Hazard Codes Xn;N,N,Xn,T
Risk Statements 20/21/22-50/53-25-21-20
Safety Statements 13-60-61-45
OEBB
OELTWA: 5 mg/m3
RIDADR UN 2811
RTECS WH8750000
TSCA No
HazardClass 6.1(b)
PackingGroup III
Hazardous Substances Data13121-70-5(Hazardous Substances Data)
ToxicityLD50 in adult male, female rats (mg/kg): 779, 826 orally (Gaines, Linder)

Cyhexatin Usage And Synthesis

DescriptionCyhexatin is a colorless to white, nearly odorless, crystalline powder. Molecular weight=385.16;Boiling point=227℃(decomposes); Freezing/Meltingpoint=195-198℃. Practically insoluble in water
Chemical PropertiesCyhexatin is a colorless to white, nearly odor-less, crystalline powder.
UsesCyhexatin is a derivative of tricyclohexyltin and an effective acaricide used in the control of spider mites.
UsesAcaricide.
UsesCyhexatin is used to control the motile stages of phytophagousmites on pome and stone fruit, vines, hops, cotton, vegetables andornament ah.
DefinitionChEBI: Cyhexatin is an organotin acaricide.
General DescriptionTechnical Cyhexatin is a nearly odorless white crystalline powder that has no true melting point but degrades to bis(tricyclohexyl)tin oxide at 121 to 131°C which decomposes at 228°C; a melting point of 195-198°C is also reported. Very insoluble in water (less than 1 mg/L at 25°C), but wettable by water. Soluble in some organic solvents (acetone 1.3 g/L; xylenes 3.6 g/L; carbon tetrachloride 28 g/L; dichloromethane 34 g/L). Used as an acaricide (an agent to kill plant-feeding mites) in almonds, walnuts, hops and some fruits.
Reactivity ProfileCyhexatin is incompatible with strong oxidizing agents. Soluble in some organic solvents (acetone 1.3 g/L; xylenes 3.6 g/L; carbon tetrachloride 28 g/L; dichloromethane 34 g/L). Stable in aqueous suspensions in neutral and alkaline pH (above pH 6), but reacts exothermically as a base in the presence of strong acids to form salts. Converts to dicyclohexyltin oxide and further to cyclohexylstannoic acid upon exposure to ultraviolet radiation.
Safety ProfilePoison by ingestion, inhalation, and intraperitoneal routes. Moderately toxic by skin contact. Experimental reproductive effects. When heated to decomposition it emits acrid smoke and irritating fumes. See also TIN COMPOUNDS.
Potential ExposureUsed as an agricultural chemical andpesticide. A potential danger to those involved in the manu-facture, formulation, and application of this acaricide(miticide).
First aidIf this chemical gets into the eyes, remove anycontact lenses at once and irrigate immediately for at least15 min, occasionally lifting upper and lower lids. Seek medical attention immediately. If this chemical contacts theskin, remove contaminated clothing and wash immediatelywith soap and water. Speed in removing material from skinis of extreme importance. Shampoo hair promptly if contaminated. Seek medical attention immediately. If thischemical has been inhaled, remove from exposure, beginrescue breathing (using universal precautions, includingresuscitation mask) if breathing has stopped and CPR ifheart action has stopped. Transfer promptly to a medicalfacility. When this chemical has been swallowed, get medical attention. Give large quantities of water and inducevomiting. Do not make an unconscious person vomit.
Metabolic pathwayThere is little published information of the degradation and metabolismof cyhexatin. However, useful information on the fate of cyhexatin in awater/sediment system can be deduced from published data onazoc yclotin.
storageColor Code—Blue: Health Hazard/Poison: Storein a secure poison location. Prior to working with thischemical you should be trained on its proper handling andstorage. Store in tightly closed containers in a cool, dark,well-ventilated area away from oxidizers.
ShippingUN2786 Organotin pesticides, solid, toxic,Hazard Class: 6.1; Labels: 6.1-Poisonous material. UN2811Toxic solids, organic, n.o.s., Hazard Class: 6.1; Labels: 6.1-Poisonous materials, Technical Name Required.
DegradationCyhexatin is stable to hydrolysis at temperatures up to 100 °C fromslightly acid (pH 6) to alkaline conditions (PM).
IncompatibilitiesIncompatible with strong oxidizers. Mayreact exothermically as base in the Incompatible withstrong oxidizers. May react exothermically as base in theIncompatible with strong oxidizers. Reacts exothermicallyas base in the presence of strong acids, forming salts. Keep away from ultraviolet radiation which may cause conver-sion to dicyclohexyltin oxide and further to cyclohexylstan-noic acid.

Cyhexatin Preparation Products And Raw materials

Raw materialsTRICYCLOHEXYLTIN CHLORIDE
Preparation ProductsAzocyclotin
Cyhalofop-butyl CAS 122008-85-9
Cymoxanil CAS 57966-95-7
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