Josiphos SL-J009-1 Pd G3 CAS 1702311-34-9
Introduction：Basic information about Josiphos SL-J009-1 Pd G3 CAS 1702311-34-9, including its chemical name, molecular formula, synonyms, physicochemical properties, and safety information, etc.
Josiphos SL-J009-1 Pd G3 Basic informationReaction
| Product Name: | Josiphos SL-J009-1 Pd G3 |
| Synonyms: | Chloro{(R)-(-)-1-[(S)-2-(dicyclohexylphosphino)ferrocenyl]ethyldi-t-butylphosphine}(2'-amino-1,1'-biphenyl-2-yl)palladium(II);JOSIPHOS Palladacycle Gen. 3;Methanesulfonato{(R)-(-)-1-[(S)-2-(dicyclohexylphosphino)ferrocenyl]ethyldi-t-butylphosphine}(2'-amino-1,1'-biphenyl-2-yl)palladium(II);METHANESULFONATO{(R)-(-)-1-[(S)-2-(DICYCLOHEXYLPHOSPHINO)FERROCENYL]ETHYLDI-T-BUTYLPHOSPHINE}(2'-AMINO-1,1'-BIPHENYL-2-YL)PALLADIUM(II),MIN.98%[JOSIPHOSPALLADACYCLEGEN.3];Methanesulfonato{(R)-(-)-1-[(S)-2-(dicyclohexylphosphino)ferrocenyl]ethyldi-t-butylphosphine}(2'-amino-1,1'-biphenyl-2-yl)palladium(II),[Josiphos Palladacycle Gen. 3];BRUNO PALLADACYCLE;Josiphos Pd G3;Methanesulfonato{(R)-(-)-1-[(S)-2-(dicyclohexylphosphino)ferrocenyl]ethyldi-t-butylphosphine}(2'-amino-1,1'-biphenyl-2-yl)palladium(II)Josiphos Pd G3 |
| CAS: | 1702311-34-9 |
| MF: | C45H66FeNO3P2PdS10*- |
| MW: | 925.287962 |
| EINECS: | |
| Product Categories: | |
| Mol File: | 1702311-34-9.mol |
Josiphos SL-J009-1 Pd G3 Chemical Properties
| Melting point | 180-186 °C |
| storage temp. | 2-8°C, protect from light, stored under nitrogen |
| form | solid |
| color | red-orange |
| InChIKey | VXSQFQJKYCLYAK-DHOIFHORSA-N |
| SMILES | NC1=C(C=CC=C1)C2=C([Pd]OS(C)(=O)=O)C=CC=C2.C[C@@H](P(C(C)(C)C)C(C)(C)C)[C]3[C](P(C4CCCCC4)C5CCCCC5)[C][C][C]3.[C]6[C][C][C][C]6.[Fe] |
Safety Information
| WGK Germany | WGK 3 |
| Storage Class | 11 - Combustible Solids |
| Reaction | Catalyst used for C-O coupling reactions between electron-deficient phenols and functionalized heteroaryl chlorides. |
| Uses | Josiphos SL-J009-1 Pd G3 is a good catalyst, widely used in various cross-coupling reactions, including: Buchwald-Hartwig cross-coupling reaction, Hiyama Coupling, Negishi Coupling, Heck Reaction, Sonogashira Coupling and Suzuki-Miyaura Coupling, etc. |
| General Description | Josiphos SL-J009-1 Pd G3 (Josiphos SL-J009-1-G3-palladacycle) is a modified G3 precatalyst (G3′). It has been synthesized by Buchwald and coworkers from second generation (G2) precatalyst by methylation of the amino group present on biphenyl backbone. It is a useful catalyst for various cross-coupling reactions. G3 precatalysts are versatile catalysts. They have long life in solution and are readily soluble in various organic solvents. G3- precatalysts have been employed in various C-N bond forming reactions. |
| reaction suitability | reaction type: Buchwald-Hartwig Cross Coupling Reaction reaction type: Cross Couplings reaction type: Heck Reaction reaction type: Hiyama Coupling reaction type: Negishi Coupling reaction type: Sonogashira Coupling reaction type: Stille Coupling reaction type: Suzuki-Miyaura Coupling reagent type: catalyst |
Josiphos SL-J009-1 Pd G3 Preparation Products And Raw materials
