P(t-Bu)3 Pd G4 CAS 1621274-11-0

Introduction:Basic information about P(t-Bu)3 Pd G4 CAS 1621274-11-0, including its chemical name, molecular formula, synonyms, physicochemical properties, and safety information, etc.

P(t-Bu)3 Pd G4 Basic informationReactions

Product Name:P(t-Bu)3 Pd G4
Synonyms:P(t-Bu)3 Pd G4;Methanesulfonato(tri-t-butylphosphino)(2'-methylamino-1,1'-biphenyl-2-yl)palladium(II),[P(t-Bu)3 Palladacycle Gen. 4];METHANESULFONATO(TRI-T-BUTYLPHOSPHINO)(2'-METHYLAMINO-1,1'-BIPHENYL-2-YL)PALLADIUM(II),98%[P(T-BU)3PALLADACYCLEGEN.4];P(t-Bu)3 Palladacycle Gen. 4;Methanesulfonato(tri-t-butylphosphino)(2'-methylamino-1,1'-biphenyl-2-yl)palladium(II);P(t-Bu)3 Pd G4 / Methanesulfonato(tri-t-butylphosphino)(2'-methylamino-1,1'-biphenyl-2-yl)palladium(II);Methanesulfonato(tri-t-butylphosphino)(2'-methylamino-1,1'-biphenyl-2-yl)palladium(II) ISO 9001:2015 REACH;1-biphenyl-2-yl)palladium(II)
CAS:1621274-11-0
MF:C26H42NO3PPdS
MW:586.08
EINECS:
Product Categories:
Mol File:1621274-11-0.mol

P(t-Bu)3 Pd G4 Chemical Properties

storage temp. 2-8°C, protect from light, stored under nitrogen
form Powder
color tan to yellow
InChIInChI=1S/C14H15N.3C4H10P.O3S.Pd/c1-11-7-3-4-8-12(11)13-9-5-6-10-14(13)15-2;3*1-4(2,3)5;1-4(2)3;/h3-10,15H,1-2H3;3*5H,1-3H3;;/q;4*-1;+1
InChIKeyJBZFBSFINJJLAH-UHFFFAOYSA-N
SMILESCC1=CC=CC=C1C1=CC=CC=C1NC.[Pd-2](S([O-])(=O)=O)(PC(C)(C)C)(PC(C)(C)C)PC(C)(C)C
CAS DataBase Reference1621274-11-0

Safety Information

WGK Germany WGK 3
Storage Class11 - Combustible Solids

P(t-Bu)3 Pd G4 Usage And Synthesis

Reactions
  1. Alternative Pd-catalyzed cross-coupling reaction of s-BuB(OH)2 and 4-chloroanisole.
  2. Alternative Pd-catalyzed cross-coupling reaction of secondary alkylboronic acids and aryl chlorides.
  3. Alternative Pd-catalyzed cross-coupling reaction of secondary alkyltrifluoroborates and aryl chlorides
Chemical PropertiesP(t-Bu)3 Pd G4 is a powder or crystalsis,it's stable, soluble in most organic solvents.
UsesP(t-Bu)3 Pd G4 is a powerful ligand for classic cross-coupling reactions combined with the Buchwald Fourth Generation Palladacycle. Bench stable, soluble in most organic solvents.
reaction suitabilityreaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Cross Couplings
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: catalyst

P(t-Bu)3 Pd G4 Preparation Products And Raw materials

P-(METHYLTHIO)PHENYLACETONITRILE CAS 38746-92-8
P,P′-(9,9-Dimethyl-9H-xanthene-4,5-diyl)bis[N,N,N′,N′-tetraethyl-phosphonous diamide] 97% CAS 349100
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