PDPP-TT CAS 1260685-66-2
Introduction:Basic information about PDPP-TT CAS 1260685-66-2, including its chemical name, molecular formula, synonyms, physicochemical properties, and safety information, etc.
PDPP-TT Basic informationClassification OFET and Sensing Applications Photovoltaic Applications
| Product Name: | PDPP-TT |
| Synonyms: | PDPP-TT;Poly[[2,3,5,6-tetrahydro-2,5-bis(2-octyldodecyl)-3,6-dioxopyrrolo[3,4-c]pyrrole-1,4-diyl]-2,5-thiophenediylthieno[3,2-b]thiophene-2,5-diyl-2,5-thiophenediyl];DPP-DTT;DPP-DTT; PDPP2T-TT-OD;DPPT-TT/DPP-DTT;PDPP2TBT;Poly[2,5-(2-octyldodecyl)-3,6-diketopyrrolopyrrole-alt-5,5-(2,5-di(thien-2-yl)thieno [3,2-b]thiophene)];PDPPT-TT |
| CAS: | 1260685-66-2 |
| MF: | (C60H88N2O2S4)n |
| MW: | 0 |
| EINECS: | |
| Product Categories: | |
| Mol File: | 1260685-66-2.mol |
PDPP-TT Chemical Properties
| solubility | Chloroform, chlorobenzene and dichlorobenzene |
Safety Information
| Classification | Bithiophene, Thienothiophene, Organic semiconducting materials, Low band-gap polymers, Organic photovoltaics, Polymer solar cells, OFETs. |
| OFET and Sensing Applications | The exceptional high mobility of this polymer of up to 10 cm2/Vs [2] via solution-processed techniques, combined with its intrinsic air stability (even during annealing) has made PDPP2T-TT-OD of significant interest for OFET and sensing purposes. While the highest mobilities require exceptional molecular weights of around 500 kD (and with commensurate solubility issues), high mobilities in the region of 1-3 cm2/Vs can still be achieved with good solution-processing at around 250 kD. Example OFET characteristics for DPP-DTT (M313) solution processed from chlorobenzene on a 300 nm SiO2 substrate treated with OTS. Output characteristic (top left), transfer curves (top right), mobility fitting (bottom left) and calculated mobility. |
| Photovoltaic Applications | Although shown as a promising hole-mobility polymer for OFETs, when used as the donor material in a bulk heterojunction photovoltaic (with PC70BM as the acceptor), initial efficiencies of 1.6% were achieved for DPP-DTT. The low device metrics were attributed to poor film morphology. However, a higher efficiency of 6.9% was achieved by using thicker film (220 nm). PDPP2T-TT-OD has also recently been used successfully as an active-layer dopant material in PTB7-based devices. An improvement in device performance was observed, with average efficiencies increasing from 7.6% to 8.3% when the dopant concentration of DPP-DTT was 1 wt%. The use of DPP-DTT as a high-mobility hole-interface layer for perovskite hybrid devices has also been investigated. |
| Description | DPP-DTT is a high mobility p-type polymer, suitable for OFET and sensing and photovoltaic applications. |
