CAS 490023-37-5|(11bS)-N-Benzyl-N-methyldinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepi

Introduction：Basic information about CAS 490023-37-5|(11bS)-N-Benzyl-N-methyldinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepi, including its chemical name, molecular formula, synonyms, physicochemical properties, and safety information, etc.

Table of Contents

1. Names
2. Chemical & Physical Properties
3. Safety Information
4. Customs
5. Articles2
6. Synonyms

Common Name	(11bS)-N-Benzyl-N-methyldinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine
CAS Number	490023-37-5	Molecular Weight	435.453
Density	/	Boiling Point	635.4±48.0 °C at 760 mmHg
Molecular Formula	C₂₈H₂₂NO₂P	Melting Point	155-159ºC
MSDS	ChineseUSA	Flash Point	338.1±29.6 °C

Names

Name	N-Benzyl-N-methyldinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine
Synonym	More Synonyms

Chemical & Physical Properties

Boiling Point	635.4±48.0 °C at 760 mmHg
Melting Point	155-159ºC
Molecular Formula	C₂₈H₂₂NO₂P
Molecular Weight	435.453
Flash Point	338.1±29.6 °C
Exact Mass	435.138824
PSA	29.52000
LogP	7.91
Vapour Pressure	0.0±1.9 mmHg at 25°C
InChIKey	OHGGHRJGBXAKKY-UHFFFAOYSA-N
SMILES	CN(Cc1ccccc1)p1oc2ccc3ccccc3c2c2c(ccc3ccccc32)o1
Storage condition	2-8°C

Safety Information

Personal Protective Equipment	Eyeshields;Gloves;type N95 (US);type P1 (EN143) respirator filter
Hazard Codes	Xi
Risk Phrases	36/37/38
Safety Phrases	26-36/37/39
RIDADR	NONH for all modes of transport
HS Code	2921499090

Customs

HS Code	2921499090
Summary	2921499090 other aromatic monoamines and their derivatives; salts thereof VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:30.0%

Articles2

Highly enantioselective rhodium-catalyzed hydrogenation of beta-dehydroamino acid derivatives using monodentate phosphoramidites.

J. Am. Chem. Soc. 124 , 14552, (2002)

New and very easily accessible monodentate phosphoramidite ligands have been developed that lead to excellent ee's and full conversions in the hydrogenation of (E)- and (Z)-beta-dehydroamino acid deri...

J. Organomet. Chem. 692 , 428, (2007)

Synonyms

Dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine, N-methyl-N-(phenylmethyl)-

(S)-(+)-Benzyl(3,5-dioxa-4-phospha-cyclohepta[2,1-a

MFCD04117686

N-Benzyl-N-methyldinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine

3,4-a′]dinaphthalen-4-yl)methylamine

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