CAS 5815-08-7|tert-Butoxy bis(dimethylamino)methane
| Common Name | tert-Butoxy bis(dimethylamino)methane | ||
|---|---|---|---|
| CAS Number | 5815-08-7 | Molecular Weight | 174.284 |
| Density | 0.9±0.1 g/cm3 | Boiling Point | 176.9±20.0 °C at 760 mmHg |
| Molecular Formula | C9H22N2O | Melting Point | / |
| MSDS | ChineseUSA | Flash Point | 35.2±19.0 °C |
| Symbol | GHS02, GHS07 | Signal Word | Warning |
Names
| Name | Bredereck’s reagent |
|---|---|
| Synonym | More Synonyms |
Chemical & Physical Properties
| Density | 0.9±0.1 g/cm3 |
|---|---|
| Boiling Point | 176.9±20.0 °C at 760 mmHg |
| Molecular Formula | C9H22N2O |
| Molecular Weight | 174.284 |
| Flash Point | 35.2±19.0 °C |
| Exact Mass | 174.173218 |
| PSA | 15.71000 |
| LogP | 2.14 |
| Vapour Pressure | 1.1±0.3 mmHg at 25°C |
| Index of Refraction | 1.446 |
| InChIKey | HXRAMSFGUAOAJR-UHFFFAOYSA-N |
| SMILES | CN(C)C(OC(C)(C)C)N(C)C |
| Storage condition | Freezer (-20°C) |
Safety Information
| Symbol | GHS02, GHS07 |
|---|---|
| Signal Word | Warning |
| Hazard Statements | H226-H315-H319-H335 |
| Precautionary Statements | P261-P305 + P351 + P338 |
| Personal Protective Equipment | Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter |
| Hazard Codes | Xi: Irritant; |
| Risk Phrases | R10;R36/37/38 |
| Safety Phrases | S26 |
| RIDADR | UN 1993 3/PG 3 |
| WGK Germany | 3 |
| Packaging Group | III |
| Hazard Class | 3 |
| HS Code | 2922199090 |
Customs
| HS Code | 2922199090 |
|---|---|
| Summary | 2922199090. other amino-alcohols, other than those containing more than one kind of oxygen function, their ethers and esters; salts thereof. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:30.0% |
Articles5
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| Macrocyclization by nickel-catalyzed, ester-promoted, epoxide-alkyne reductive coupling: total synthesis of (-)-gloeosporone. Angew. Chem. Int. Ed. Engl. 48(29) , 5366-8, (2009) Ringing the changes: The total synthesis of the title compound centers around a novel strategy that employs a nickel(0)-phosphine complex and triethyl borane in an efficient closure of a 14-membered r... | |
| First total synthesis of the 2,7-naphthyridine alkaloids lophocladine a and B. Arch. Pharm. (Weinheim) 339(12) , 677-9, (2006) The one-pot reaction of 4-benzylpyridine-3-carbonitrile with Bredereck's reagent and subsequent treatment with either glacial acetic acid and sulfuric acid or ammonium acetate provided the new bioacti... |
Synonyms
| Bredereck’s reagent |
| Methanediamine, 1-(1,1-dimethylethoxy)-N,N,N',N'-tetramethyl- |
| tert-Butoxy bis(dimethylamino)methane |
| EINECS 227-383-9 |
| tert-butoxybis(dimethylamino)methane |
| Brederick’s reagent |
| MFCD00042858 |
| N,N,N',N'-Tetramethyl-1-[(2-methyl-2-propanyl)oxy]methanediamine |
| 1-tert-Butoxy-N,N,N',N'-tetramethylmethanediamine |
| EINECS 227-383-9 |
