CAS 10038-98-9|Germanium chloride
| Common Name | Germanium chloride | ||
|---|---|---|---|
| CAS Number | 10038-98-9 | Molecular Weight | 214.45200 |
| Density | 1.844 | Boiling Point | 82-84ºC |
| Molecular Formula | Cl4Ge | Melting Point | -49.5ºC |
| MSDS | ChineseUSA | Flash Point | 83.1°C |
| Symbol | GHS05, GHS06 | Signal Word | Danger |
Names
| Name | Germanium tetrachloride |
|---|---|
| Synonym | More Synonyms |
Chemical & Physical Properties
| Density | 1.844 |
|---|---|
| Boiling Point | 82-84ºC |
| Melting Point | -49.5ºC |
| Molecular Formula | Cl4Ge |
| Molecular Weight | 214.45200 |
| Flash Point | 83.1°C |
| Exact Mass | 213.79700 |
| LogP | 2.37720 |
| Vapour Pressure | 76 mm Hg ( 20 °C) |
| Index of Refraction | 1.4644 |
| Water Solubility | DECOMPOSES |
Toxicological Information
CHEMICAL IDENTIFICATION |
ACUTE TOXICITY DATA - TYPE OF TEST :
- Standard Draize test
- ROUTE OF EXPOSURE :
- Administration into the eye
- SPECIES OBSERVED :
- Rodent - rabbit
- REFERENCE :
- GTPZAB Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1-36, 1957-1992. For publisher information, see MTPEEI Volume(issue)/page/year: 8(4),57,1964 ** ACUTE TOXICITY DATA **
- TYPE OF TEST :
- LC50 - Lethal concentration, 50 percent kill
- ROUTE OF EXPOSURE :
- Inhalation
- SPECIES OBSERVED :
- Rodent - mouse
- DOSE/DURATION :
- 44 gm/m3/2H
- TOXIC EFFECTS :
- Sense Organs and Special Senses (Eye) - conjunctive irritation Behavioral - somnolence (general depressed activity) Lungs, Thorax, or Respiration - other changes
- REFERENCE :
- GTPZAB Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1-36, 1957-1992. For publisher information, see MTPEEI Volume(issue)/page/year: 12(5),51,1968
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Intravenous
- SPECIES OBSERVED :
- Rodent - mouse
- DOSE/DURATION :
- 56 mg/kg
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- REFERENCE :
- CSLNX* U.S. Army Armament Research & Development Command, Chemical Systems Laboratory, NIOSH Exchange Chemicals. (Aberdeen Proving Ground, MD 21010) Volume(issue)/page/year: NX#02625 ** OTHER MULTIPLE DOSE TOXICITY DATA **
- TYPE OF TEST :
- TCLo - Lowest published toxic concentration
- ROUTE OF EXPOSURE :
- Inhalation
- SPECIES OBSERVED :
- Rodent - mouse
- DOSE/DURATION :
- 500 mg/m3/2H/40D-I
- TOXIC EFFECTS :
- Lungs, Thorax, or Respiration - structural or functional change in trachea or bronchi Blood - hemorrhage Related to Chronic Data - death
- REFERENCE :
- GTPZAB Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1-36, 1957-1992. For publisher information, see MTPEEI Volume(issue)/page/year: 8(4),57,1964 *** OCCUPATIONAL EXPOSURE LIMITS *** OEL-RUSSIA:STEL 1 mg/m3 JAN 1993 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - X5834 No. of Facilities: 7 (estimated) No. of Industries: 1 No. of Occupations: 2 No. of Employees: 1717 (estimated) No. of Female Employees: 195 (estimated)
Safety Information
| Symbol | GHS05, GHS06 |
|---|---|
| Signal Word | Danger |
| Hazard Statements | H314-H330 |
| Supplemental HS | Reacts violently with water. |
| Precautionary Statements | P260-P280-P284-P305 + P351 + P338-P310 |
| Personal Protective Equipment | Faceshields;full-face respirator (US);Gloves;Goggles;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter |
| Hazard Codes | C:Corrosive; |
| Risk Phrases | R14;R34 |
| Safety Phrases | S25-S36/37/39-S45-S8 |
| RIDADR | UN 3390 |
| WGK Germany | 3 |
| RTECS | LY5225000 |
| Packaging Group | II |
Articles5
More Articles| Electrochemical vapor deposition of semiconductors from gas phase with a solid membrane cell. J. Am. Chem. Soc. 137 , 6638-42, (2015) We demonstrate the feasibility of semiconductor deposition via the electrochemical reduction of gaseous precursors by the use of an anhydrous proton-conducting membrane, the solid acid CsHSO4, at 165 ... | |
| The Crystal Structure and Raman Spectrum of Ge(5)Cl(12).GeCl(4) and the Vibrational Spectrum of Ge(2)Cl(6). Inorg. Chem. 37 , 6032, (1998) The Raman spectrum of Ge(2)Cl(6) shows close analogies with that of the isoelectronic [Ga(2)Cl(6)](2)(-). A band at 262 cm(-)(1) is assigned as principally a Ge-Ge stretching mode. The compound is ver... | |
| Catalytic conversion of carbohydrates into 5-hydroxymethylfurfural by germanium(IV) chloride in ionic liquids. ChemSusChem 4(1) , 131-8, (2011) Direct conversion of carbohydrates into 5-hydroxymethylfurfural (HMF) catalyzed by germanium(IV) chloride in ionic liquids has been investigated in search of an efficient and environmentally friendly ... |
Synonyms
| tetrachloro-german |
| Germanium(IV) Chloride (Metals Basis) |
| germanium(IV) chloride |
| tetrachloro-germaniu |
| GERMANIUM(+4)CHLORIDE |
| germanium(IV) tetrachloride |
| MFCD00011029 |
| germaniumtetrachloride |
| EINECS 233-116-7 |
| tetrachlorogermanium |
| germanium chloride |
| tetrachloro-Germane |
| GeCl4 |
| Germane,tetrachloro |
