CAS 583844-38-6|((4s,5s)-(-)-o-[1-benzyl-1-(5-methyl-2-phenyl-4,5-dihydrooxazol-4-yl)-2-pheny

Introduction：Basic information about CAS 583844-38-6|((4s,5s)-(-)-o-[1-benzyl-1-(5-methyl-2-phenyl-4,5-dihydrooxazol-4-yl)-2-pheny, including its chemical name, molecular formula, synonyms, physicochemical properties, and safety information, etc.

Table of Contents

1. Names
2. Chemical & Physical Properties
3. Safety Information
4. Articles2
5. Synonyms

Common Name	((4s,5s)-(-)-o-[1-benzyl-1-(5-methyl-2-phenyl-4,5-dihydrooxazol-4-yl)-2-phenylethyl]-dicyclohexyl-phosphinite)(1,5-cod)iridium (i) tetrakis(3,5-bis(trifluoromethyl)phenylborate
CAS Number	583844-38-6	Molecular Weight	1731.35000
Density	/	Boiling Point	/
Molecular Formula	C₇₇H₇₀BF₂₄IrNO₂P	Melting Point	160-161ºC
MSDS	USA	Flash Point	/

Names

Name	((4S,5S)-(-)-O-[1-Benzyl-1-(5-methyl-2-phenyl-4,5-dihydrooxazol-4-yl)-2-phenylethyl]-dicyclohexylphosphinite)(1,5-COD)iridium(I) tetrakis(3,5-bis(trifluoromethyl)phenylborate (S,S)-[COD]Ir[c
Synonym	More Synonyms

Chemical & Physical Properties

Melting Point	160-161ºC
Molecular Formula	C₇₇H₇₀BF₂₄IrNO₂P
Molecular Weight	1731.35000
Exact Mass	1731.45000
PSA	44.41000
LogP	22.55120
InChIKey	LADOFGASZSKWMF-FWAHSXEBSA-N
SMILES	CC1OC(c2ccccc2)=NC1C(Cc1ccccc1)(Cc1ccccc1)OP(C1CCCCC1)C1CCCCC1.FC(F)(F)c1cc([B-](c2cc(C(F)(F)F)cc(C(F)(F)F)c2)(c2cc(C(F)(F)F)cc(C(F)(F)F)c2)c2cc(C(F)(F)F)cc(C(F)(F)F)c2)cc(C(F)(F)F)c1.[CH]1[CH]CC[CH][CH]CC1.[Ir]

Safety Information

Personal Protective Equipment	Eyeshields;Gloves;type N95 (US);type P1 (EN143) respirator filter
Safety Phrases	22-24/25
RIDADR	NONH for all modes of transport
HS Code	28439000

Articles2

A New Class of Modular Phosphinite-Oxazoline Ligands: Ir-Catalyzed Enantioselective Hydrogenation of Alkenes We thank Dr. Martin Studer and Dr. Beno_t Pugin (Solvias AG, Basel) for fruitful discussions, and Prof. Kevin Burgess (Texas A&M University) for preprints of related unpublished work. Financial support by the Swiss National Science Foundation is gratefully acknowledged.

Angew. Chem. Int. Ed. Engl. 40 , 4445-4447, (2001)

Threonine-derived phosphinite-oxazoline ligands for the Ir-catalyzed enantioselective hydrogenation. Menges, F. and Pfaltz, A.

Adv. Synth. Catal. 344 , 40-44, (2002)

Synonyms

MFCD06658139

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