CAS 782495-18-5|(S)-1,1,1-TRIFLUORO-N-(PYRROLIDIN-2-YLMETHYL)METHANESULFONAMIDE

Introduction:Basic information about CAS 782495-18-5|(S)-1,1,1-TRIFLUORO-N-(PYRROLIDIN-2-YLMETHYL)METHANESULFONAMIDE, including its chemical name, molecular formula, synonyms, physicochemical properties, and safety information, etc.
Common Name(S)-1,1,1-TRIFLUORO-N-(PYRROLIDIN-2-YLMETHYL)METHANESULFONAMIDE
CAS Number782495-18-5Molecular Weight232.22400
Density/Boiling Point/
Molecular FormulaC6H11F3N2O2SMelting Point205-215°C
MSDSChineseUSAFlash Point/
Symbol
GHS05
Signal WordDanger

Names

Name1,1,1-trifluoro-N-[[(2S)-pyrrolidin-2-yl]methyl]methanesulfonamide
SynonymMore Synonyms

Chemical & Physical Properties

Melting Point205-215°C
Molecular FormulaC6H11F3N2O2S
Molecular Weight232.22400
Exact Mass232.04900
PSA66.58000
LogP1.97810
InChIKeyRIWFUAUXWIEOTK-YFKPBYRVSA-N
SMILESO=S(=O)(NCC1CCCN1)C(F)(F)F
Storage condition2-8°C

Safety Information

Symbol
GHS05
Signal WordDanger
Hazard StatementsH314
Precautionary StatementsP280-P305 + P351 + P338-P310
Personal Protective EquipmentEyeshields;Faceshields;full-face particle respirator type N100 (US);Gloves;respirator cartridge type N100 (US);type P1 (EN143) respirator filter;type P3 (EN 143) respirator cartridges
Hazard CodesC: Corrosive;
Risk Phrases34
Safety Phrases26-36/37/39-45
RIDADRUN 3263 8/PG 3
Hazard Class8.0
HS Code2935009090

Customs

HS Code2935009090
Summary2935009090 other sulphonamides VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:35.0%

Articles3

More Articles
A recyclable fluorous (S)-pyrrolidine sulfonamide promoted direct, highly enantioselective Michael addition of ketones and aldehydes to nitroolefins in water.

Org. Lett. 8 , 3077-3079, (2006)

[reaction: see text] A recycle and reusable fluorous (S)-pyrrolidine sulfonamide organocatalyst has been developed for promoting highly enantio- and diastereoselective Michael addition reactions of ke...

Highly enantioselective aldol reactions catalyzed by a recyclable fluorous (S) pyrrolidine sulfonamide on water.

Org. Lett. 10 , 1211-1214, (2008)

Fluorous (S) pyrrolidine sulfonamide serves as an efficient promoter for highly enantioselective aldol reactions of ketones and aldehydes with aromatic aldehydes on water. A notable feature of the org...

Direct, highly enantioselective pyrrolidine sulfonamide catalyzed Michael addition of aldehydes to nitrostyrenes.

Angew. Chem. Int. Ed. Engl. 44 , 1369-1371, (2005)

Synonyms

(S)-1,1,1-Trifluoro-N-(pyrrolidin-2-ylmethyl)methanesulfonamide
N-[(2S)-2-PYRROLIDINYLMETHYL]-TRIFLUOROMETHANESULFONAMIDE
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