CAS 17501-44-9|2,4-Pentanedione-zirconium (4:1)

Introduction:Basic information about CAS 17501-44-9|2,4-Pentanedione-zirconium (4:1), including its chemical name, molecular formula, synonyms, physicochemical properties, and safety information, etc.
Common Name2,4-Pentanedione-zirconium (4:1)
CAS Number17501-44-9Molecular Weight491.687
Density/Boiling Point187.6ºC at 760 mmHg
Molecular FormulaC20H32O8ZrMelting Point171-173ºC
MSDSChineseUSAFlash Point71.9ºC
Symbol
GHS07
Signal WordWarning

Names

NameZirconium(IV) Acetylacetonate
SynonymMore Synonyms

Chemical & Physical Properties

Boiling Point187.6ºC at 760 mmHg
Melting Point171-173ºC
Molecular FormulaC20H32O8Zr
Molecular Weight491.687
Flash Point71.9ºC
Exact Mass490.114410
PSA136.56000
LogP2.21800
InChIKeyYOBOXHGSEJBUPB-SMVDYOEFSA-N
SMILESCC(=O)C=C(C)O.CC(=O)C=C(C)O.CC(=O)C=C(C)O.CC(=O)C=C(C)O.[Zr]
Storage conditionStore below +30°C.
Water Solubility14g/l

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
ZH9280000
CHEMICAL NAME :
Zirconium, tetrakis(2,4-pentanedionato-O,O')-
CAS REGISTRY NUMBER :
17501-44-9
LAST UPDATED :
199712
DATA ITEMS CITED :
23
MOLECULAR FORMULA :
C20-H28-O8-Zr
MOLECULAR WEIGHT :
487.70
WISWESSER LINE NOTATION :
1V1V1 2 &-ZR-

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Intraperitoneal
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
316 mg/kg
TOXIC EFFECTS :
Peripheral Nerve and Sensation - flaccid paralysis without anesthesia (usually neuromuscular blockage) Sense Organs and Special Senses (Eye) - effect, not otherwise specified Lungs, Thorax, or Respiration - dyspnea
REFERENCE :
NTIS** National Technical Information Service. (Springfield, VA 22161) Formerly U.S. Clearinghouse for Scientific & Technical Information. Volume(issue)/page/year: AD441-640
TYPE OF TEST :
LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE :
Ocular
SPECIES OBSERVED :
Rodent - guinea pig
DOSE/DURATION :
100 mg/kg
TOXIC EFFECTS :
Sense Organs and Special Senses (Eye) - lacrimation Sense Organs and Special Senses (Eye) - corneal damage
REFERENCE :
NTIS** National Technical Information Service. (Springfield, VA 22161) Formerly U.S. Clearinghouse for Scientific & Technical Information. Volume(issue)/page/year: AD441-640 *** REVIEWS *** ACGIH TLV-TWA 5 mg(Zr)/m3; STEL 10 mg(Zr)/m3 DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices (BEIs) booklet issues by American Conference of Governmental Industrial Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year: TLV/BEI,1997 ACGIH TLV-Not classifiable as a human carcinogen DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices (BEIs) booklet issues by American Conference of Governmental Industrial Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year: TLV/BEI,1997 *** U.S. STANDARDS AND REGULATIONS *** MSHA STANDARD-air:TWA 5 mg(Zr)/m3 DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices (BEIs) booklet issues by American Conference of Governmental Industrial Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year: 3,285,1971 OSHA PEL (Gen Indu):8H TWA 5 mg(Zr)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1910.1000,1994 OSHA PEL (Construc):8H TWA 5 mg(Zr)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1926.55,1994 OSHA PEL (Shipyard):8H TWA 5 mg(Zr)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1915.1000,1993 OSHA PEL (Fed Cont):8H TWA 5 mg(Zr)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 41,50-204.50,1994 *** OCCUPATIONAL EXPOSURE LIMITS *** OEL-AUSTRALIA:TWA 5 mg(Zr)/m3;STEL 10 mg(Zr)/m3 JAN 1993 OEL-BELGIUM:TWA 5 mg(Zr)/m3;STEL 10 mg(Zr)/m3 JAN 1993 OEL-DENMARK:TWA 5 mg(Zr)/m3 JAN 1993 OEL-FINLAND:TWA 5 mg(Zr)/m3 JAN 1993 OEL-GERMANY:TWA 5 mg(Zr)/m3 JAN 1993 OEL-HUNGARY:STEL 5 mg(Zr)/m3 JAN 1993 OEL-THE NETHERLANDS:TWA 5 mg(Zr)/m3 JAN 1993 OEL-THE PHILIPPINES:TWA 5 mg(Zr)/m3 JAN 1993 OEL-SWITZERLAND:TWA 5 mg(Zr)/m3 JAN 1993 OEL-TURKEY:TWA 5 mg(Zr)/m3 JAN 1993 OEL-UNITED KINGDOM:TWA 5 mg(Zr)/m3;STEL 10 mg(Zr)/m3 JAN 1993 OEL IN BULGARIA, COLOMBIA, JORDAN, KOREA check ACGIH TLV OEL IN NEW ZEALAND, SINGAPORE, VIETNAM check ACGIH TLV

Safety Information

Symbol
GHS07
Signal WordWarning
Hazard StatementsH302 + H312 + H332-H315-H319-H335
Precautionary StatementsP261-P280-P305 + P351 + P338
Personal Protective Equipmentdust mask type N95 (US);Eyeshields;Gloves
Hazard CodesXn
Risk PhrasesR22
Safety PhrasesS22-S36/37
RIDADRNONH for all modes of transport
WGK Germany3
RTECSZH9280000
HS Code2914509090

Customs

HS Code2914509090
SummaryHS:2914509090 other ketones with other oxygen function VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:5.5% General tariff:30.0%

Articles1

More Articles
Trzaska, S.T. et al.

Chem. Mater. 11 , 130, (1999)

Synonyms

2,4-Pentanedione, zirconium salt (4:1)
Zirconium(IV) 2,4-pentanedionate
Tetrakis(2,4-pentanedionato)zirconium
2,4-Pentanedione zirconium(IV) derivative
Zirconium(IV) acetylacetonate
Tetrakis(2,4-pentanedionato)zirconium(IV)
EINECS 241-510-5
MFCD00000036
2,4-Pentanedione - zirconium (4:1)
Acetylacetone Zirconium(IV) Salt
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