CAS 925-90-6|ETHYLMAGNESIUM BROMIDE

Introduction:Basic information about CAS 925-90-6|ETHYLMAGNESIUM BROMIDE, including its chemical name, molecular formula, synonyms, physicochemical properties, and safety information, etc.
Common NameETHYLMAGNESIUM BROMIDE
CAS Number925-90-6Molecular Weight133.27000
Density1.02 g/mL at 25 °CBoiling Point34.6°C
Molecular FormulaC2H5BrMgMelting Point-116.3°C
MSDSChineseFlash Point<−30 °F
Symbol
GHS02, GHS05
Signal WordDanger

Names

NameEthylmagnesium Bromide
SynonymMore Synonyms

Chemical & Physical Properties

Density1.02 g/mL at 25 °C
Boiling Point34.6°C
Melting Point-116.3°C
Molecular FormulaC2H5BrMg
Molecular Weight133.27000
Flash Point<−30 °F
Exact Mass131.94300
LogP1.81950
InChIKeyFRIJBUGBVQZNTB-UHFFFAOYSA-M
SMILES[Br-].[CH2-]C.[Mg+2]
Storage conditionwater-free area

Safety Information

Symbol
GHS02, GHS05
Signal WordDanger
Hazard StatementsH225-H250-H260-H314
Supplemental HSMay form explosive peroxides., Reacts violently with water.
Precautionary StatementsP210-P222-P223-P231 + P232-P370 + P378-P422
Personal Protective EquipmentFaceshields;full-face respirator (US);Gloves;Goggles;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter
Hazard CodesF+:Extremelyflammable;Xn:Harmful;C:Corrosive;
Risk PhrasesR12;R15;R19;R22;R34
Safety PhrasesS16-S26-S36/37/39-S43-S45-S7/8-S27
RIDADRUN 3399 4.3/PG 1
WGK Germany1
Packaging GroupI
Hazard Class4.3
HS Code2931900090

Customs

HS Code2931900090
Summary2931900090. other organo-inorganic compounds. VAT:17.0%. Tax rebate rate:13.0%. Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward). MFN tariff:6.5%. General tariff:30.0%

Articles7

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New reagent system for attaining high regio- and stereoselectivities in allylic displacement of 4-cyclopentene-1,3-diol monoacetate with aryl- and alkenylmagnesium bromides.

Org. Lett. 7(2) , 183-6, (2005)

[Reaction: see text] Low regioselectivity of RMgBr (R = aryl, alkenyl) in the CuCN-catalyzed reaction with 4-cyclopentene-1,3-diol monoacetate is improved by addition of LiCl or MgCl2 to a similar ext...

Rhodococcus opacus strain PD630 as a new source of high-value single-cell oil? Isolation and characterization of triacylglycerols and other storage lipids.

Microbiology 146 ( Pt 5) , 1143-9, (2000)

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Studies of the formation of all-carbon quaternary centres, en route to lyngbyatoxin A. A comparison of phenyl and 7-substituted indole systems.

Org. Biomol. Chem. 2(10) , 1447-55, (2004)

Copper mediated allylic substitutions and conjugate additions to geranyl, cinnamyl and allylic indole compounds have been investigated with the aim of finding a method for the creation of the all-carb...

Synonyms

ethylmagnesium bromide
MFCD00000043
EINECS 213-127-3
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