Introduction:Basic information about (RP)-1-[(R)-α-(DiMethylaMino)-2-(diphenylphosphino)benzyl]-2-diphenylphosphinoferrocene CAS 1003012-, including its chemical name, molecular formula, synonyms, physicochemical properties, and safety information, etc.
(RP)-1-[(R)-α-(DiMethylaMino)-2-(diphenylphosphino)benzyl]-2-diphenylphosphinoferrocene Basic informationReactions
| Product Name: | (RP)-1-[(R)-α-(DiMethylaMino)-2-(diphenylphosphino)benzyl]-2-diphenylphosphinoferrocene |
| Synonyms: | (RP)-1-[(R)-α-(Dimethylamino)-2-(diphenylphosphino)benzyl]-2-diphenylphosphinoferrocene;(R)-(-)-[(R)-2-Diphenylphosphinoferrocenyl](N,N-diMethylaMino)(2-diphenylphosphinophenyl)Methane,Min.97%;Taniaphos SL-T001-1, (2S)-1-[(R)-(Dimethylamino)[2-(diphenylphosphino)phenyl]methyl]-2-(diphenylphosphino)ferrocene (acc to CAS);(R)-(-)-[(R)-2-Diphenylphosphinoferrocenyl](N,N-dimethylamino)(2-diphenylphosphinophenyl)methane, min. 97%;(R)-(+)-[(R)-2-Diphenylphosphinoferrocenyl](N,N-dimethylamino)(2- diphenylphosphinophenyl)methane, min. 97%;(R)-1-Diphenylphosphino-2-[(R)-a-(N,N-dimethylamino)-o-(diphenylphosphinophenyl)-methyl]ferrocene;(RP)-1-[(R)-alpha-(Dimethylamino)-2-(diphenylphosphino)benzyl]-2-diphenylphosphinoferrocene optical purity ee: >=99%;(2S)-1-[(R)-(Dimethylamino)[2-(diphenylphosphino)phenyl]methyl]-2-(diphenylphosphino)ferrocene |
| CAS: | 1003012-96-1 |
| MF: | C45H45FeNP2 |
| MW: | 717.638022 |
| EINECS: | |
| Product Categories: | organometallic complex |
| Mol File: | 1003012-96-1.mol |
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(RP)-1-[(R)-α-(DiMethylaMino)-2-(diphenylphosphino)benzyl]-2-diphenylphosphinoferrocene Chemical Properties
| alpha | +312° ±15° (c 0.5, CHCl3) |
| storage temp. | 2-8°C |
| form | Powder |
| color | orange |
| Stability: | store cold |
| InChIKey | DEHRMLQYTSYVBC-VROLVAQFSA-N |
| SMILES | [Fe].[CH]1[CH][CH][CH][CH]1.CN(C)[C@@H]([C]2[CH][CH][CH][C]2P(c3ccccc3)c4ccccc4)c5ccccc5P(c6ccccc6)c7ccccc7 |
| CAS DataBase Reference | 1003012-96-1 |
Safety Information
| WGK Germany | 3 |
| HS Code | 29319090 |
| Storage Class | 11 - Combustible Solids |
(RP)-1-[(R)-α-(DiMethylaMino)-2-(diphenylphosphino)benzyl]-2-diphenylphosphinoferrocene Usage And Synthesis
| Reactions | - Ligand for copper-catalyzed asymmetric allylic alkylation of halocrotonates
- Ligand for silver-catalyzed asymmetric 1,3-dipolar cycloadditions of α-iminonitriles
- Ligand for copper-catalyzed enantioselective reductive couplings of alkenylazaarenes with ketones
- Ligand for copper-catalyzed chiral Mannich-type reactions of γ-butenolides and N-thiophosphinoyl ketimines
- Ligand for palladium-catalyzed asymmetric borylation
- Ligand for copper-catalyzed enantiodivergent hydroboration of bicyclic alkenes
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| Chemical Properties | Orange powder |
| General Description | sold in collaboration with Solvias AG |
(RP)-1-[(R)-α-(DiMethylaMino)-2-(diphenylphosphino)benzyl]-2-diphenylphosphinoferrocene Preparation Products And Raw materials