3-Iodo-9H-carbazole CAS 16807-13-9
Introduction：Basic information about 3-Iodo-9H-carbazole CAS 16807-13-9, including its chemical name, molecular formula, synonyms, physicochemical properties, and safety information, etc.
3-Iodo-9H-carbazole Basic information
| Product Name: | 3-Iodo-9H-carbazole |
| Synonyms: | 3-Iodo-9H-carbazole;3-Iodocarbazole;3-iodo-9H-carbzole;9H-Carbazole, 3-iodo-;3-Iodocarbazole >3-Iodo-9H-carbazole ISO 9001：2015 REACH;TIANFU-CHEM 3-Iodocarbazole-;3-Iodine-9H-carbazole |
| CAS: | 16807-13-9 |
| MF: | C12H8IN |
| MW: | 293.1 |
| EINECS: | |
| Product Categories: | |
| Mol File: | 16807-13-9.mol |
3-Iodo-9H-carbazole Chemical Properties
| Melting point | 195-197℃ |
| Boiling point | 430.6±18.0 °C(Predicted) |
| density | 1.854 |
| storage temp. | Keep in dark place,Sealed in dry,Room Temperature |
| form | powder to crystal |
| pka | 16.54±0.30(Predicted) |
| color | White to Light yellow to Light orange |
| λmax | 340nm(CH3CN)(lit.) |
| InChI | InChI=1S/C12H8IN/c13-8-5-6-12-10(7-8)9-3-1-2-4-11(9)14-12/h1-7,14H |
| InChIKey | OYIGWMXXIFYAGD-UHFFFAOYSA-N |
| SMILES | N1C2=C(C=CC=C2)C2=C1C=CC(I)=C2 |
Safety Information
| HS Code | 2933.99.8290 |
| Description | 3-Iodo-9H-carbazole is a chemical compound used in the research and development of organic materials for optoelectronic devices, such as OLEDs (organic light-emitting diodes). It has also been studied for its potential use in pharmaceuticals. It may cause skin and eye irritation, respiratory issues, and other health hazards if not handled properly. Therefore, it must be stored in a well-ventilated area, away from heat sources or combustible materials. |
| Synthesis | A solution of 9H-carbazole (5.57g, 33.3 mmol) and KI (3.68g, 22.2 mmol) in AcOH (92 mL) was heated to 100 °C for 1 h. KI03 (3.57g, 16.7 mmol) was added in portions to the solution, and the resulting mixture was stirred for another 2 h at 100°C. The mixture was poured into water (500 mL), and the precipitation was collected by filtration and washed with hot water. Recrystallization was made in DCM to afford 6.8 g (70 percent) of product 3-Iodo-9H-carbazole as a white solid. |
| References | [1] Patent: WO2006/104221, 2006, A1. Location in patent: Page/Page column 70-71 [2] Patent: WO2007/26626, 2007, A1. Location in patent: Page/Page column 54-55 [3] Journal of Organic Chemistry, 2015, vol. 80, # 4, p. 2392 - 2396 [4] Patent: WO2014/153043, 2014, A1. Location in patent: Paragraph 0166 [5] Patent: CN103694992, 2016, B. Location in patent: Paragraph 0092-0095 |
3-Iodo-9H-carbazole Preparation Products And Raw materials
| Raw materials | Carbazole-->Potassium iodate-->Acetic acid-->Potassium iodide |
| Preparation Products | carbazol-3-ylamine-->9-Phenyl-9H,9'H-[3,3']bicarbazolyl-->9H-Carbazole, 9-ethyl-3-iodo- |
