Introduction：Basic information about 9-Fluorenemethanol CAS 24324-17-2, including its chemical name, molecular formula, synonyms, physicochemical properties, and safety information, etc.
9-Fluorenemethanol Basic information
| Product Name: | 9-Fluorenemethanol |
| Synonyms: | Fluorenemethanol;(ethylthio)formic acid (5-nitro-1-indazolyl)methyl ester;TIMTEC-BB SBB008508;AKOS MSC-0133;Fmoc-Oh(9-Fluorenylmethanol);9-Fluorenylmethanol,98+%;9-FLUORENYLMENTHANOL;Fmoc (9-Fluorenemethanol) |
| CAS: | 24324-17-2 |
| MF: | C14H12O |
| MW: | 196.24 |
| EINECS: | 246-167-5 |
| Product Categories: | Fluorenes;Fluorenes & Fluorenones;Amino alcohols;Alkohols;N-Protecting Reagents;Fluorene Derivatives;Peptide coupling agents;Amino Acid Derivatives;Benzocycles;Fluorenes, Flurenones |
| Mol File: | 24324-17-2.mol |
|
9-Fluorenemethanol Chemical Properties
| Melting point | 105-107 °C (lit.) |
| Boiling point | 293.14°C (rough estimate) |
| density | 1.0304 (rough estimate) |
| refractive index | 1.5385 (estimate) |
| storage temp. | Sealed in dry,Room Temperature |
| solubility | Soluble in methanol. |
| pka | 13.68±0.10(Predicted) |
| form | Crystalline Powder |
| color | White to pale yellow |
| BRN | 2330017 |
| InChI | InChI=1S/C14H12O/c15-9-14-12-7-3-1-5-10(12)11-6-2-4-8-13(11)14/h1-8,14-15H,9H2 |
| InChIKey | XXSCONYSQQLHTH-UHFFFAOYSA-N |
| SMILES | C1(CO)C2=C(C=CC=C2)C2=C1C=CC=C2 |
| CAS DataBase Reference | 24324-17-2(CAS DataBase Reference) |
| NIST Chemistry Reference | Fluorene-9-methanol(24324-17-2) |
| EPA Substance Registry System | 9H-Fluorene-9-methanol (24324-17-2) |
Safety Information
| Hazard Codes | Xi |
| Risk Statements | 36/37/38 |
| Safety Statements | 22-24/25-36/37/39-27-26 |
| WGK Germany | 3 |
| Hazard Note | Irritant |
| TSCA | TSCA listed |
| HS Code | 29062900 |
| Storage Class | 11 - Combustible Solids |
9-Fluorenemethanol Usage And Synthesis
| Chemical Properties | WHITE TO PALE YELLOW CRYSTALLINE POWDER |
| Uses | 9-Fluorenylmethanol(FMOC-OH) acts as a N-protecting reagent, which is used in the synthesis of peptide. It is also used in the preparation of deoxynucleoside 9-fluorenemethyl phosphorodithioates. Further, it is used to prepare 9-(fluoromethyl)fluorene. In addition to this, it is involved in the electropolymerization with boron trifluoride diethyl etherate to yield low-potential electrodeposition of semiconducting poly(9-fluorenemethanol) film. |
| Uses | 9-Fluorenemethanol(FMOC-OH), N-protecting reagent, was used in the peptide syntheses. 9-Fluorenemethanol was also used in the synthesis of deoxynucleoside 9-fluorenemethyl phosphorodithioates. |
| Reactions | Electropolymerization of 9-fluorenemethanol in boron trifluoride diethyl etherate leads to low-potential electrodeposition of semiconducting poly(9-fluorenemethanol) (PFMO) film. |
| General Description | Vibrational spectroscopy of jet-cooled 9-fluorenemethanol and its clusters 9-fluorenemethanol-H2O, 9-fluorenemethanol-CH3OH, 9-fluorenemethanol-C2H5OH and 9-fluorenemethanol-C3H7OH has been studied by IR-UV double-resonance method. |
9-Fluorenemethanol Preparation Products And Raw materials
| Raw materials | 9H-Fluorene-9-methanol acetate-->9-Carboxyfluorene |
| Preparation Products | 9-Fluorenylmethyl chloroformate-->4-Methylbenzyl alcohol-->9-Methylene-9H-fluorene-->FMOC-ASP(OFM)-OH-->(9H-fluoren-9-yl)methyl 4-methylbenzene-1-sulfonate-->Fmoc-OSu-->CYSTEINE(FM)-OH |
9H-3,9'-bicarbazole-1,1',2,2',3',4,4',5,5',6,6',7,7',8,8
