bis(3-Methoxyphenyl)aMine CAS 92248-06-1
bis(3-Methoxyphenyl)aMine Basic information
| Product Name: | bis(3-Methoxyphenyl)aMine |
| Synonyms: | bis(3-Methoxyphenyl)aMine;Benzenamine, 3-methoxy-N-(3-methoxyphenyl)-;3-Methoxy-N-(3-methoxyphenyl)aniline;bis(3-Methoxyphenyl)aMine ISO 9001：2015 REACH |
| CAS: | 92248-06-1 |
| MF: | C14H15NO2 |
| MW: | 229.27 |
| EINECS: | |
| Product Categories: | |
| Mol File: | 92248-06-1.mol |
bis(3-Methoxyphenyl)aMine Chemical Properties
| Boiling point | 175-178 °C(Press: 0.8 Torr) |
| density | 1.126±0.06 g/cm3(Predicted) |
| storage temp. | Keep in dark place,Inert atmosphere,Room temperature |
| pka | 0.14±0.50(Predicted) |
Safety Information
| Synthesis | 10365-98-7 536-90-3 92248-06-1 General procedure for the synthesis of bis(3-methoxyphenyl)amines from 3-methoxyphenylboronic acid and m-aminoanisole:1. copper acetate (2.1 mmol) and pyridine (0.25 mL) were added to a vigorously stirred solution of anhydrous dichloromethane (3.5 mL) of 3-methoxyaniline (1 mmol) and 3-methoxyphenylboronic acid (2 mmol) under nitrogen protection.2. The reaction mixture was stirred at room temperature for 72 hours, during which time the progress of the reaction was monitored by thin layer chromatography (TLC).3. Upon completion of the reaction, the crude reaction mixture was pre-adsorbed onto silica gel and the target product, bis(3-methoxyphenyl)amine (3c), was subsequently isolated by fast column chromatography.4. Product yield: 25%; EI-MS m/z: 229 (M+) [Ref: Urgaonkar, S.; Verkade, J.G. J. Org. Chem. 2004, 69, 9135-9142]. |
| References | [1] Patent: WO2007/79593, 2007, A1. Location in patent: Page/Page column 31 |
bis(3-Methoxyphenyl)aMine Preparation Products And Raw materials
| Raw materials | 3-Methoxyphenylboronic acid-->Phenol, 3-[(3-methoxyphenyl)amino]--->3-Bromoanisole-->Iodomethane-->m-Anisidine-->N,N,N',N'-Tetramethylethylenediamine-->Pyridine-->Dichloromethane |
| Preparation Products | 2,7-Dimethoxy-9H-Carbazole |
