DIETHYLPHOSPHORAMIDOUS DICHLORIDE CAS 1069-08-5
Introduction：Basic information about DIETHYLPHOSPHORAMIDOUS DICHLORIDE CAS 1069-08-5, including its chemical name, molecular formula, synonyms, physicochemical properties, and safety information, etc.
DIETHYLPHOSPHORAMIDOUS DICHLORIDE Basic information
| Product Name: | DIETHYLPHOSPHORAMIDOUS DICHLORIDE |
| Synonyms: | DICHLORO(DIETHYLAMINO)PHOSPHINE;(DIETHYLAMINO)PHOSPHONOUS DICHLORIDE;(DIETHYLAMINO)DICHLOROPHOSPHINE;DIETHYLPHOSPHORAMIDOUS DICHLORIDE;N,N-Diethylphosphoramidous Dichloride;Diethylphosphoramidous dichloride,97%;(Diethylamido)dichlorophosphite;(Diethylamino)phosphine dichloride |
| CAS: | 1069-08-5 |
| MF: | C4H10Cl2NP |
| MW: | 174.01 |
| EINECS: | 628-166-5 |
| Product Categories: | wq;Catalysis and Inorganic Chemistry;Phosphorus Compounds;Phosphorus Precursors |
| Mol File: | 1069-08-5.mol |
DIETHYLPHOSPHORAMIDOUS DICHLORIDE Chemical Properties
| Boiling point | 179 °C (lit.) |
| density | 1.196 g/mL at 25 °C (lit.) |
| refractive index | n |
| Fp | 181 °F |
| storage temp. | 2-8°C |
| pka | -1.49±0.70(Predicted) |
| form | Liquid |
| color | Clear colorless |
| Water Solubility | Reacts violently in water. |
| Sensitive | Moisture Sensitive |
| InChI | InChI=1S/C4H10Cl2NP/c1-3-7(4-2)8(5)6/h3-4H2,1-2H3 |
| InChIKey | BPEMCEULJQTJMI-UHFFFAOYSA-N |
| SMILES | P(N(CC)CC)(Cl)Cl |
| CAS DataBase Reference | 1069-08-5(CAS DataBase Reference) |
Safety Information
| Hazard Codes | C |
| Risk Statements | 34 |
| Safety Statements | 26-36/37/39-43-45 |
| RIDADR | UN 3265 8/PG 2 |
| WGK Germany | 3 |
| HazardClass | 8 |
| PackingGroup | II |
| HS Code | 29310099 |
| Storage Class | 8A - Combustible corrosive hazardous materials |
| Hazard Classifications | Skin Corr. 1B |
| Chemical Properties | DIETHYLPHOSPHORAMIDOUS DICHLORIDE is clear colorless to light yellow liquid |
| Uses | DIETHYLPHOSPHORAMIDOUS DICHLORIDE is a useful reagent for the efficient phosphorylation of alcohols. |
| Uses | Dichloro(diethylamino)phosphine is used as a reagent for the preparation of diethylaminophosphine-metal complexes and it is a critical starting material in the preparation of various phosphines, phosphoramidites & the phosphitylation of alcohols. |
| Uses | Reagent for the preparation of diethylaminophosphine-metal complexes and the phosphitylation of alcohols. |
| reaction suitability | reaction type: Buchwald-Hartwig Cross Coupling Reaction reaction type: Heck Reaction reaction type: Hiyama Coupling reaction type: Negishi Coupling reaction type: Sonogashira Coupling reaction type: Stille Coupling reaction type: Suzuki-Miyaura Coupling reagent type: ligand |
DIETHYLPHOSPHORAMIDOUS DICHLORIDE Preparation Products And Raw materials
| Preparation Products | BIS(3,5-DI(TRIFLUOROMETHYL)PHENYL)CHLOROPHOSPHINE-->N,N-DIETHYL-1,5-DIHYDRO-2,4,3-BENZODIOXAPHOSPHEPIN-3-AMINE-->BIS(DIETHYLAMINO)CHLOROPHOSPHINE-->Dimethyl N,N-Diethyl Phosphoramidite |
