Introduction：Basic information about Diphenyl carbonate CAS 102-09-0, including its chemical name, molecular formula, synonyms, physicochemical properties, and safety information, etc.
Diphenyl carbonate Basic information
| Product Name: | Diphenyl carbonate |
| Synonyms: | AURORA 16157;CARBONIC ACID DIPHENYL ESTER;DIPHENYL CARBONATE;DPC;LABOTEST-BB LT01417418;PHENYL CARBONATE;Phenol carbonate;phenylcarbonate((pho)2co) |
| CAS: | 102-09-0 |
| MF: | C13H10O3 |
| MW: | 214.22 |
| EINECS: | 203-005-8 |
| Product Categories: | Pyridines ,Heterocyclic Acids;Color Former & Related Compounds;Functional Materials;Sensitizer;Carbonates;Carbonyl Compounds;Organic Building Blocks;102-09-0;bc0001;KT00001 |
| Mol File: | 102-09-0.mol |
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Diphenyl carbonate Chemical Properties
| Melting point | 79-82 °C (lit.) |
| Boiling point | 301-302 °C (lit.) |
| density | 1,3 g/cm3 |
| vapor pressure | 0.014Pa at 20℃ |
| refractive index | 1.5090 (estimate) |
| Fp | 168 °C |
| storage temp. | Sealed in dry,Room Temperature |
| solubility | Chloroform (Slightly), Methanol (Slightly) |
| form | Flakes or Crystalline Powder |
| color | White |
| Water Solubility | Insoluble |
| Merck | 14,7278 |
| BRN | 1074863 |
| Stability: | Stable. Incompatible with strong oxidizing agents. Flammable. |
| InChI | 1S/C13H10O3/c14-13(15-11-7-3-1-4-8-11)16-12-9-5-2-6-10-12/h1-10H |
| InChIKey | ROORDVPLFPIABK-UHFFFAOYSA-N |
| SMILES | O=C(Oc1ccccc1)Oc2ccccc2 |
| LogP | 3.21 at 25℃ |
| CAS DataBase Reference | 102-09-0(CAS DataBase Reference) |
| NIST Chemistry Reference | Diphenyl carbonate(102-09-0) |
| EPA Substance Registry System | Carbonic acid, diphenyl ester (102-09-0) |
Safety Information
| Hazard Codes | Xn |
| Risk Statements | 22-20 |
| Safety Statements | 22-24/25 |
| RIDADR | 3077 |
| WGK Germany | 1 |
| RTECS | FG0500000 |
| TSCA | TSCA listed |
| HazardClass | 9 |
| PackingGroup | III |
| HS Code | 29209010 |
| Storage Class | 13 - Non Combustible Solids |
| Hazard Classifications | Acute Tox. 4 Oral
Aquatic Acute 1
Aquatic Chronic 2 |
| Hazardous Substances Data | 102-09-0(Hazardous Substances Data) |
| Toxicity | rat,LD50,oral,1500mg/kg (1500mg/kg),BEHAVIORAL: CONVULSIONS OR EFFECT ON SEIZURE THRESHOLD,National Technical Information Service. Vol. OTS0540144, |
Diphenyl carbonate Usage And Synthesis
| Chemical Properties | white solid |
| Uses | In the molten state as solvent for nitrocellulose. |
| Uses | Estrogenic activity of Diphenyl Carbonate by yeast 2-hybrid assay was studied. |
| Preparation | Diphenyl carbonate is prepared by passing phosgene into a solution ofphenol in aqueous sodium hydroxide in the presence of an inert solvent suchas methylene chloride:
The organic phase, which contains the diphenyl carbonate, is separated; thesolvent is stripped off and the diphenyl carbonate is purified by distillation.The reaction is accelerated by tertiary amines and is analogous to theinterfacial polycondensation of 2,2-bis(4'hydroxyphenyl)propane and phosgenedescribed. Diphenyl carbonate is a white crystallinesolid, m.p. 78??C. |
| Definition | ChEBI: A carbonate ester that is the diphenyl ester of carbonic acid. |
| Flammability and Explosibility | Non flammable |
| Safety Profile | Questionable carcinogen with experimental neoplastigenic and tumorigenic data. When heated to decomposition it emits acrid smoke and irritating fumes |
Diphenyl carbonate Preparation Products And Raw materials
| Raw materials | Sodium hydroxide-->Hydrogen-->Phenol-->PHOSGENE-->CARBON MONOXIDE-->calcium diphenoxide-->Vinylene carbonate-->Tetraphenylphosphonium chloride-->METHYL PHENYL CARBONATE-->phenyl 4,5-dichloro-6-oxopyridazine-1(6H)-carboxylate-->3-tert-Butylphenol-->Hexamethylene Diisocyanate |
| Preparation Products | Polycarbonate-->1,5-Diphenylcarbazide-->Diphenyl N-cyanocarbonimidate-->2,4-bis[1-(4-hydroxyphenyl)isopropyl]phenol-->4-Amino-2,4-dihydro-5-(1-methylethyl)-3H-1,2,4-triazol-3-one-->Bisphenol TMC-->1H-BenziMidazole-7-carboxylic acid, 1-[[2'-(2,5-dihydro-5-oxo-1,2,4-oxadiazol-3-yl)[1,1'-biphenyl]-4-yl]Methyl] -2-ethoxy-, Methyl ester |
