DIPHENYL(P-TOLYL)PHOSPHINE CAS 1031-93-2

Introduction：Basic information about DIPHENYL(P-TOLYL)PHOSPHINE CAS 1031-93-2, including its chemical name, molecular formula, synonyms, physicochemical properties, and safety information, etc.

DIPHENYL(P-TOLYL)PHOSPHINE Basic information

• Product Name: DIPHENYL(P-TOLYL)PHOSPHINE
• Synonyms: 1-[5-chloro-2-[4-chloro-2-[[(3,4-dichloroanilino)-oxomethyl]amino]phenoxy]phenyl]-3-(3,4-dichlorophenyl)urea;P-TOLYLDIPHENYLPHOSPHINE;Phosphine, (4-methylphenyl)diphenyl-;DIPHENYL(P-TOLYL)PHOSPHINE;DIPHENYL-4-TOLYLPHOSPHINE;DIPHENYL-4-METHYLPHENYLPHOSPHINE;p-Tolyldiphenylphosphine,min.96%;p-Tolyldiphenylphosphine, 96+%
• CAS: 1031-93-2
• MF: C19H17P
• MW: 276.31
• EINECS: 213-848-3
• Product Categories: Achiral Phosphine;Aryl Phosphine;organophosphorus ligand;Ligand;Catalysis and Inorganic Chemistry;Phosphine Ligands;Phosphorus Compounds
• Mol File: 1031-93-2.mol

DIPHENYL(P-TOLYL)PHOSPHINE Chemical Properties

• Melting point: 66-68 °C (lit.)
• Boiling point: 250 °C(Press: 14 Torr)
• storage temp.: 2-8°C
• form: crystal
• color: white
• BRN: 646709
• InChI: InChI=1S/C19H17P/c1-16-12-14-19(15-13-16)20(17-8-4-2-5-9-17)18-10-6-3-7-11-18/h2-15H,1H3
• InChIKey: QJIMTLTYXBDJFC-UHFFFAOYSA-N
• SMILES: P(C1=CC=C(C)C=C1)(C1=CC=CC=C1)C1=CC=CC=C1
• CAS DataBase Reference: 1031-93-2(CAS DataBase Reference)

Safety Information

• Hazard Codes: Xi
• Risk Statements: 36/37/38-38-37-36
• Safety Statements: 26-37/39-39-37
• WGK Germany: 3
• PackingGroup: III
• HS Code: 29319090
• Storage Class: 11 - Combustible Solids
• Hazard Classifications: Eye Irrit. 2 Skin Irrit. 2 STOT SE 3

DIPHENYL(P-TOLYL)PHOSPHINE Usage And Synthesis

Chemical Properties

white to light yellow crystal powde

Uses

Reactant for:

• Three-component cyclization
• Probing coordination ability via a palladium pincer complex
• Chelation-assisted hydroacylation of olefins with primary alcohols

Reactant for synthesis of:

• Trinuclear ruthenium carbonyl triarylphosphine cluster complexes
• Leishmanicidal leads targeting mitochondria through inhibition of the respiratory complex
• InP nanofibers / metal phosphide nanostructures
• Peroxyl radical cations via pulse radiolysis one-electron oxidations

Synthesis Reference(s)

The Journal of Organic Chemistry, 52, p. 748, 1987 DOI: 10.1021/jo00381a008

reaction suitability

reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: ligand