DIPHENYLIODONIUM CHLORIDE CAS 1483-72-3

Introduction：Basic information about DIPHENYLIODONIUM CHLORIDE CAS 1483-72-3, including its chemical name, molecular formula, synonyms, physicochemical properties, and safety information, etc.

DIPHENYLIODONIUM CHLORIDE Basic information

• Product Name: DIPHENYLIODONIUM CHLORIDE
• Synonyms: DIPHENYLIODONIUM CHLORIDE;chlorodiphenyliodonium;diphenyl-iodoniuchloride;Iodonium,diphenyl-,chloride;Diphenyliodinium;Iodonium,diphenyl-chloride;DIPHENYLIODONIUM CHLORIDE 97%;Diphenyliodonium chloride,97%
• CAS: 1483-72-3
• MF: C12H10I.Cl
• MW: 316.57
• EINECS: 216-049-8
• Product Categories: Diphenyliodonium Compounds;Hypervalent Iodine Compounds;Iodonium Sulfonium & Oxonium Compounds;Synthetic Organic Chemistry;Hypervalent Iodine;Oxidation;Synthetic Reagents
• Mol File: 1483-72-3.mol

DIPHENYLIODONIUM CHLORIDE Chemical Properties

• Melting point: 233-235 °C (subl.) (lit.)
• density: 1.6151 (estimate)
• storage temp.: Keep in dark place,Sealed in dry,Room Temperature
• solubility: soluble in Methanol
• form: Powder
• color: White to light cream-yellow
• Water Solubility: Soluble in water and methanol.
• Sensitive: Light Sensitive
• Merck: 14,7464
• BRN: 3574977
• InChI: InChI=1S/C12H10I.ClH/c1-3-7-11(8-4-1)13-12-9-5-2-6-10-12;/h1-10H;1H/q+1;/p-1
• InChIKey: RSJLWBUYLGJOBD-UHFFFAOYSA-M
• SMILES: [I+](C1C=CC=CC=1)C1C=CC=CC=1.[Cl-]
• CAS DataBase Reference: 1483-72-3(CAS DataBase Reference)
• EPA Substance Registry System: Iodonium, diphenyl-, chloride (1483-72-3)

Safety Information

• Hazard Codes: T,Xi
• Risk Statements: 25-36/37/38
• Safety Statements: 26-36
• RIDADR: UN 2811 6.1/PG 3
• WGK Germany: 3
• RTECS: NN6651666
• F: 8
• TSCA: TSCA listed
• HazardClass: 6.1
• PackingGroup: III
• HS Code: 29319090
• Storage Class: 6.1C - Combustible acute toxic Cat.3 toxic compounds or compounds which causing chronic effects
• Hazard Classifications: Acute Tox. 3 Oral Eye Irrit. 2 Skin Irrit. 2 STOT SE 3

DIPHENYLIODONIUM CHLORIDE Usage And Synthesis

Chemical Properties

WHITE TO LIGHT CREAM-YELLOW POWDER

Uses

Diphenyliodonium chloride is used as a reagent for electrophilic phenylation . It is used as a reactant for copper-catalyzed cross coupling reactions of purinesband arylation of anilines. It is involved in the preparation of acetylenic arylselenide and (arylmethylene)oxindoles. Further, it is employed in the preparation of aryl alkynes through Sonogashira coupling reactions.

Uses

Reactant for:

• Copper-catalyzed cross coupling reactions of purines and diaryliodonium salts
• Synthesis of acetylenic arylselenides
• Sonogashira coupling reactions for the preparation of aryl alkynes
• C-H functionalization for synthesis of (arylmethylene)oxindoles
• Arylation of anilines
• Studies on the visible-light photosensitive system-dlourescein yellow-bis(di-Ph iodonium)
• Investigating the properties of direct and sensitized photolysis of dispersed photoacid generators

reaction suitability

reagent type: oxidant

storage

Diphenyliodonium chloride is stable; can be stored at rt without decomposition.