Introduction：Basic information about Mordant Orange 1 CAS 2243-76-7, including its chemical name, molecular formula, synonyms, physicochemical properties, and safety information, etc.
Mordant Orange 1 Basic information
| Product Name: | Mordant Orange 1 |
| Synonyms: | MORDANT ORANGE 1;P-NITROBENZENEAZOSALICYLIC ACID SODIUM SALT;ORANGE R;TIMTEC-BB SBB008990;SODIUM P-NITROBENZENEAZOSALICYLATE;SODIUM 5-(P-NITROPHENYLAZO)SALICYLATE;synchromateorangeaor;terracotta2rn |
| CAS: | 2243-76-7 |
| MF: | C13H9N3O5 |
| MW: | 287.23 |
| EINECS: | 218-818-3 |
| Product Categories: | Azo;Analytical Chemistry;Indicator (pH);pH Indicators |
| Mol File: | 2243-76-7.mol |
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Mordant Orange 1 Chemical Properties
| Melting point | 250°C |
| Boiling point | 429.53°C (rough estimate) |
| density | 1.3681 (rough estimate) |
| refractive index | 1.5600 (estimate) |
| storage temp. | room temp |
| solubility | Soluble in water, ethanol; slightly soluble in acetone |
| pka | 11.2(at 25℃) |
| form | powder |
| Colour Index | 14030 |
| color | Orange-brown |
| PH Range | 10(Yellow)-12(Violet) |
| Water Solubility | SOLUBLE |
| ε(extinction coefficient) | ≥7000 at 266-276nm in methanol at 0.006g/L |
| λmax | 385nm |
| Merck | 14,255 |
| BRN | 962365 |
| Major Application | Display device, photoresist, nanoparticles, sensors, image-recoring materials, photoconductive materials, photography, electrorheological materials, copying materials, optical engineering applications, monitoring oil degradation, lubricant, flame luminosity enhancing agent, coloring zinc, method for polymerization of vinyl chloride, determination of OH groups on resins, cosmetics, diapers, food storage, measurement of acidity injuice, assay for aldehyde contents, determination of albumin, agent for plaque, method for counting leukocytes, antifungal agent |
| InChI | 1S/C13H9N3O5/c17-12-6-3-9(7-11(12)13(18)19)15-14-8-1-4-10(5-2-8)16(20)21/h1-7,17H,(H,18,19) |
| InChIKey | ZHFPEICFUVWJIS-BGWNKZQTSA-M |
| SMILES | OC(=O)c1cc(ccc1O)N=Nc2ccc(cc2)[N+]([O-])=O |
| CAS DataBase Reference | 2243-76-7(CAS DataBase Reference) |
| EPA Substance Registry System | Benzoic acid, 2-hydroxy-5-[(4-nitrophenyl)azo]- (2243-76-7) |
Safety Information
| Hazard Codes | Xn |
| Risk Statements | 22-36 |
| Safety Statements | 24/25-26 |
| WGK Germany | 3 |
| RTECS | VO5310000 |
| TSCA | TSCA listed |
| HS Code | 32041200 |
| Storage Class | 11 - Combustible Solids |
| Hazard Classifications | Acute Tox. 4 Oral
Eye Irrit. 2 |
Mordant Orange 1 Usage And Synthesis
| Chemical Properties | brown powder |
| Uses | Presently, azo dyes are used for coloring many different materials such as textile, leather, and plastics and for manufacturing paints and lacquers.', 'Presently, azo dyes are used for coloring many different materials such as textile, leather, plastics, food, and pharmaceuticals and for manufacturing paints and lacquers and for printings purposes as well <<<14>>> |
| Preparation | 4-Nitrobenzenamine diazotization, and 2-Hydroxybenzoic acid?coupling. |
| Properties and Applications | dark yellow orange and brown. Dye soluble in water and Etanol be golden yellow, slightly soluble in Acetone and Cellosolve, insoluble in other organic solvent. In concentrated sulfuric acid to red light yellow, shallow green light yellow after diluted produce precipitation; In concentrated nitric acid for yellow to amber solution. Dye aqueous solution to join concentrated hydrochloric acid have green yellow precipitation; Add Sodium hydroxide solution for red wheat brown. Mainly used for wool, silk, nylon dyeing, also can be in wool and silk printing. Can also be used in electrochemical silver, biological coloring and indicator, wall paper and leather tinting.
| Standard | Ironing Fastness | Light Fastness | Fulling | Persperation Fastness | Soaping | Water | | Alkali | Acid | | ISO | 2 | 4 | 4 | 1-2 | 5 | 4-5 | 4-5 | | AATCC | Dry 2,wet 5 | 4 | 4 | | 4 | 4 | 3-4 | |
| Purification Methods | The free acid is precipitated by adding HCl to an aqueous solution of the Na salt. After 2 recrystallisations from aqueous AcOH, it has m 255o(dec); [m 253-254o(dec) was reported by Hewitt & Fox J Chem Soc 79 49 1901]. The free acid recrystallises from dilute AcOH as orange brown needles. The Na salt changes colour from yellow to red when the pH is increased from 10.2 to 12.0. [Woodland et al. J Am Chem Soc 75 5835 1953, Beilstein 16 IV 372.] |
Mordant Orange 1 Preparation Products And Raw materials
| Raw materials | 4-nitrobenzenediazonium-->5-(phenylazo)salicylic acid-->4-nitrobenzenediazonium chloride-->4-NITROBENZENEDIAZONIUM TETRAFLUOROBORATE-->Sulfuric acid-->Sodium salicylate-->Salicylic acid-->Nitric acid-->4-Nitroaniline-->Salicylic acid-->4-Nitroaniline |
