N,N'-Di-sec-butyl-p-phenylenediamine CAS 101-96-2

Introduction：Basic information about N,N'-Di-sec-butyl-p-phenylenediamine CAS 101-96-2, including its chemical name, molecular formula, synonyms, physicochemical properties, and safety information, etc.

N,N'-Di-sec-butyl-p-phenylenediamine Basic information

• Product Name: N,N'-Di-sec-butyl-p-phenylenediamine
• Synonyms: 1,4-Benzenediamine, N,N'-bis(1-methylpropyl)-;n,n’-di-s-butyl-p-phenylenediamine;N,N’-di-sec-butyl-benzene-1,4-diamine;n,n’-di-sec-butylparaphenylenediamine;n,n’-di-sec-butyl-p-phenyldiamine;n,n’-di-sec-butyl-p-phenylenediamin;n,n’-di-sek.butyl-p-fenylendiamin;N,N'-Bis(1-methylpropyl)-1,4-benzenediamine
• CAS: 101-96-2
• MF: C14H24N2
• MW: 220.35
• EINECS: 202-992-2
• Product Categories: Amines;C11 to C38;Nitrogen Compounds;efficiency antioxidant of gasoline
• Mol File: 101-96-2.mol

N,N'-Di-sec-butyl-p-phenylenediamine Chemical Properties

• Melting point: 17.8°C
• Boiling point: 159 °C / 7mmHg
• density: 0.942 g/mL at 20 °C(lit.)
• vapor pressure: 0.05Pa at 25℃
• refractive index: n20/D 1.539
• Fp: 100°C
• storage temp.: Keep in dark place,Inert atmosphere,Room temperature
• pka: 8.67±0.50(Predicted)
• form: clear liquid
• color: Light yellow to Brown to Dark red
• Water Solubility: <0.1 g/100 mL at 20 ºC
• BRN: 2805827
• Stability: Stable. Combustible.
• InChI: 1S/C14H24N2/c1-5-11(3)15-13-7-9-14(10-8-13)16-12(4)6-2/h7-12,15-16H,5-6H2,1-4H3
• InChIKey: FSWDLYNGJBGFJH-UHFFFAOYSA-N
• SMILES: CCC(C)Nc1ccc(NC(C)CC)cc1
• LogP: 0.59-3.7 at 25℃
• CAS DataBase Reference: 101-96-2(CAS DataBase Reference)
• NIST Chemistry Reference: N,N'-Di-sec-butyl-p-phenylenediamine(101-96-2)
• EPA Substance Registry System: N,N'-di-sec-Butyl-p-phenylenediamine (101-96-2)

Safety Information

• Hazard Codes: C,N,T
• Risk Statements: 25-34-43-50/53-41-38
• Safety Statements: 26-36/37/39-45-61-60
• RIDADR: UN 2922 8/PG 2
• WGK Germany: 3
• RTECS: SS9040000
• F: 10-23
• TSCA: TSCA listed
• HS Code: 2921.51.5000
• HazardClass: 6.1(b)
• PackingGroup: III
• Storage Class: 6.1A - Combustible acute toxic Cat. 1 and 2 very toxic hazardous materials
• Hazard Classifications: Acute Tox. 3 Oral Aquatic Acute 1 Aquatic Chronic 1 Eye Dam. 1 Skin Irrit. 2 Skin Sens. 1
• Hazardous Substances Data: 101-96-2(Hazardous Substances Data)
• Toxicity: LD50 oral in rat: 148mg/kg

N,N'-Di-sec-butyl-p-phenylenediamine Usage And Synthesis

Chemical Properties

dark red liquid

Uses

N,N''-di-sec-Butyl-p-phenylenediamine is used in method for preparing polyurethane adhesive.

General Description

Amber to red or dark reddish black liquid.

Air & Water Reactions

N,N'-Bis(1-methylpropyl)-1,4-phenylenediamine may be sensitive to prolonged exposure to air or light. Insoluble in water.

Reactivity Profile

N,N'-Bis(1-methylpropyl)-1,4-phenylenediamine reacts with oxidizing materials. [NTP,1992]. Neutralizes acids in exothermic reactions to form salts plus water. May be incompatible with isocyanates, halogenated organics, peroxides, phenols (acidic), epoxides, anhydrides, and acid halides. Flammable gaseous hydrogen may be generated in combination with strong reducing agents, such as hydrides.

Fire Hazard

N,N'-Bis(1-methylpropyl)-1,4-phenylenediamine is combustible.

Flammability and Explosibility

Non flammable

Safety Profile

Poison by ingestion. Moderately toxic by inhalation and sh contact. Corrosive to skin. A mild allergen. Symptoms of exposure are sweating, flushmg, shortness of breath, and slow pulse. Combustible when exposed to heat or flame; can react with oxidzing materials. To fight fire, use foam, CO2, dry chemical. When heated to decomposition it emits toxic fumes of NOx. See also AMINES.