CAS 97-99-4|Tetrahydrofurfuryl alcohol
| Common Name | Tetrahydrofurfuryl alcohol | ||
|---|---|---|---|
| CAS Number | 97-99-4 | Molecular Weight | 102.132 |
| Density | 1.0±0.1 g/cm3 | Boiling Point | 176.8±8.0 °C at 760 mmHg |
| Molecular Formula | C5H10O2 | Melting Point | -80ºC |
| MSDS | ChineseUSA | Flash Point | 83.9±0.0 °C |
| Symbol | GHS07, GHS08 | Signal Word | Danger |
Names
| Name | Tetrahydrofurfuryl Alcohol |
|---|---|
| Synonym | More Synonyms |
Chemical & Physical Properties
| Density | 1.0±0.1 g/cm3 |
|---|---|
| Boiling Point | 176.8±8.0 °C at 760 mmHg |
| Melting Point | -80ºC |
| Molecular Formula | C5H10O2 |
| Molecular Weight | 102.132 |
| Flash Point | 83.9±0.0 °C |
| Exact Mass | 102.068077 |
| PSA | 29.46000 |
| LogP | -0.39 |
| Vapour density | 3.52 (vs air) |
| Vapour Pressure | 0.3±0.7 mmHg at 25°C |
| Index of Refraction | 1.447 |
| InChIKey | BSYVTEYKTMYBMK-UHFFFAOYSA-N |
| SMILES | OCC1CCCO1 |
| Water Solubility | soluble |
Toxicological Information
CHEMICAL IDENTIFICATION |
ACUTE TOXICITY DATA - TYPE OF TEST :
- Standard Draize test
- ROUTE OF EXPOSURE :
- Administration into the eye
- SPECIES OBSERVED :
- Rodent - rabbit
- REFERENCE :
- 85JCAE "Prehled Prumyslove Toxikologie; Organicke Latky," Marhold, J., Prague, Czechoslovakia, Avicenum, 1986 Volume(issue)/page/year: -,786,1986 ** ACUTE TOXICITY DATA **
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Oral
- SPECIES OBSERVED :
- Rodent - rat
- DOSE/DURATION :
- 1600 mg/kg
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- REFERENCE :
- 38MKAJ "Patty's Industrial Hygiene and Toxicology," 3rd rev. ed., Clayton, G.D., and F.E. Clayton, eds., New York, John Wiley & Sons, Inc., 1978-82. Vol. 3 originally pub. in 1979; pub. as 2nd rev. ed. in 1985. Volume(issue)/page/year: 2C,4658,1982
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Intraperitoneal
- SPECIES OBSERVED :
- Rodent - rat
- DOSE/DURATION :
- 400 mg/kg
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- REFERENCE :
- 38MKAJ "Patty's Industrial Hygiene and Toxicology," 3rd rev. ed., Clayton, G.D., and F.E. Clayton, eds., New York, John Wiley & Sons, Inc., 1978-82. Vol. 3 originally pub. in 1979; pub. as 2nd rev. ed. in 1985. Volume(issue)/page/year: 2C,4658,1982
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Oral
- SPECIES OBSERVED :
- Rodent - mouse
- DOSE/DURATION :
- 2300 mg/kg
- TOXIC EFFECTS :
- Behavioral - general anesthetic
- REFERENCE :
- HYSAAV Hygiene and Sanitation (USSR). English translation of GISAAA. (Springfield, VA) 1964-71. Discontinued. Volume(issue)/page/year: 32(2),273,1967
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Intravenous
- SPECIES OBSERVED :
- Rodent - rabbit
- DOSE/DURATION :
- 725 mg/kg
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- REFERENCE :
- FEPRA7 Federation Proceedings, Federation of American Societies for Experimental Biology. (Bethesda, MD) V.1-46, 1942-87. Volume(issue)/page/year: 8,294,1949
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Oral
- SPECIES OBSERVED :
- Rodent - guinea pig
- DOSE/DURATION :
- 800 mg/kg
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- REFERENCE :
- 38MKAJ "Patty's Industrial Hygiene and Toxicology," 3rd rev. ed., Clayton, G.D., and F.E. Clayton, eds., New York, John Wiley & Sons, Inc., 1978-82. Vol. 3 originally pub. in 1979; pub. as 2nd rev. ed. in 1985. Volume(issue)/page/year: 2C,4658,1982
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Administration onto the skin
- SPECIES OBSERVED :
- Rodent - guinea pig
- DOSE/DURATION :
- 5 gm/kg
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- REFERENCE :
- 38MKAJ "Patty's Industrial Hygiene and Toxicology," 3rd rev. ed., Clayton, G.D., and F.E. Clayton, eds., New York, John Wiley & Sons, Inc., 1978-82. Vol. 3 originally pub. in 1979; pub. as 2nd rev. ed. in 1985. Volume(issue)/page/year: 2C,4658,1982
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Intraperitoneal
- SPECIES OBSERVED :
- Rodent - guinea pig
- DOSE/DURATION :
- 400 mg/kg
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- REFERENCE :
- 38MKAJ "Patty's Industrial Hygiene and Toxicology," 3rd rev. ed., Clayton, G.D., and F.E. Clayton, eds., New York, John Wiley & Sons, Inc., 1978-82. Vol. 3 originally pub. in 1979; pub. as 2nd rev. ed. in 1985. Volume(issue)/page/year: 2C,4658,1982 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOHS - National Occupational Hazard Survey (1974) NOHS Hazard Code - 83085 No. of Facilities: 1654 (estimated) No. of Industries: 9 No. of Occupations: 9 No. of Employees: 2169 (estimated) NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - 83085 No. of Facilities: 5004 (estimated) No. of Industries: 41 No. of Occupations: 33 No. of Employees: 81543 (estimated) No. of Female Employees: 48075 (estimated)
Safety Information
| Symbol | GHS07, GHS08 |
|---|---|
| Signal Word | Danger |
| Hazard Statements | H319-H360Df |
| Precautionary Statements | P201-P280-P305 + P351 + P338-P308 + P313-P337 + P313 |
| Personal Protective Equipment | Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter |
| Hazard Codes | Xi:Irritant; |
| Risk Phrases | R36 |
| Safety Phrases | S39 |
| RIDADR | NA 1993 / PGIII |
| WGK Germany | 2 |
| RTECS | LU2450000 |
| Packaging Group | I; II; III |
| HS Code | 29321300 |
Customs
| HS Code | 2932130000 |
|---|---|
| Summary | HS: 2932130000. (tetrahydrofuran-2-yl)methanol. VAT:17.0%. tax rebate rate:9.0%. supervision conditions:None. MFN tarrif:6.0%. general tariff:20.0% |
Articles11
More Articles| Toward surfactant-free and water-free microemulsions. J. Colloid. Interface Sci. 453 , 186-93, (2015) It was recently demonstrated that a nano-clustering was present in the monophasic "pre-Ouzo" region of ternary liquid mixtures without surfactants. The goal of this work is to check if this nano-clust... | |
| Enantioselective synthesis of 4-heterosubstituted cyclopentenones. J. Org. Chem. 78(8) , 4202-6, (2013) Racemic 4-hydroxycyclopentenone, readily derived from furfuryl alcohol, can be transformed via its O-Boc derivative to 4-acyloxy, 4-aryloxy-, 4-amino-, or 4-thio-substituted cyclopentenones with high ... | |
| Chemoselective hydrogenolysis of tetrahydrofurfuryl alcohol to 1,5-pentanediol. Chem. Commun. (Camb.) (15) , 2035-7, (2009) Direct conversion of tetrahydrofurfuryl alcohol, which is one of the biomass-derived chemicals, to 1,5-pentanediol was realized by chemoselective hydrogenolysis catalyzed by Rh/SiO(2) modified with Re... |
Synonyms
| 2-Furanmethanol, tetrahydro- |
| (Tetrahydrofuran-2-yl)methanol |
| Tetrahydrofuran-2-ylmethanol |
| EINECS 202-625-6 |
| MFCD00005372 |
| THFA |
| Tetrahydro-2-furanylmethanol |
| Tetrahydrofurfuryl alcohol |
| 2-Furanmethanol,tetrahydro- |
| T5OTJ B1Q |
| TETRAHYDROFURYL ALCOHOL |
