CAS 1686-14-2|3-Oxatricyclo[4.1.1.02,4]octane,2,7,7-trimethyl-

Introduction：Basic information about CAS 1686-14-2|3-Oxatricyclo[4.1.1.02,4]octane,2,7,7-trimethyl-, including its chemical name, molecular formula, synonyms, physicochemical properties, and safety information, etc.

Table of Contents

1. Names
2. BiologicalActivity
3. Chemical & Physical Properties
4. Toxicological Information
CHEMICAL IDENTIFICATION
HEALTH HAZARD DATA
ACUTE TOXICITY DATA
MUTATION DATA
5. Safety Information
6. Customs
7. Articles11
8. Synonyms

Common Name	3-Oxatricyclo[4.1.1.02,4]octane,2,7,7-trimethyl-
CAS Number	1686-14-2	Molecular Weight	152.23300
Density	1.027g/cm3	Boiling Point	102 - 103ºC at 30 mm Hg
Molecular Formula	C₁₀H₁₆O	Melting Point	/
MSDS	ChineseUSA	Flash Point	65.6ºC

Names

Name	α-pinene oxide
Synonym	More Synonyms

BiologicalActivity

Description	α-Pinene oxide is a natural product that can be isolated from Picea abies (L.) Karst[1].
Related Catalog	Research Areas >>OthersSignaling Pathways >>Others >>Others
References	[1]. Heemann V, et al. Gaschromatographisch-massenspektrometrische Untersuchungen der Flüchtigen Rindeninhaltsstoffe von Picea abies (L.) Karst [Volatile constituents from the bark of picea abies (L.) karst (author's transl)]. Planta Med. 1977 Dec;32(4):342-6. German.

Chemical & Physical Properties

Density	1.027g/cm3
Boiling Point	102 - 103ºC at 30 mm Hg
Molecular Formula	C₁₀H₁₆O
Molecular Weight	152.23300
Flash Point	65.6ºC
Exact Mass	152.12000
PSA	12.53000
LogP	2.20990
Index of Refraction	n20/D 1.469(lit.)
InChIKey	NQFUSWIGRKFAHK-UHFFFAOYSA-N
SMILES	CC1(C)C2CC3OC3(C)C1C2

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :: TK4565000

CHEMICAL NAME :: Pinane, 2,3-epoxy-

CAS REGISTRY NUMBER :: 1686-14-2

BEILSTEIN REFERENCE NO. :: 0080362

LAST UPDATED :: 199701

DATA ITEMS CITED :: 3

MOLECULAR FORMULA :: C10-H16-O

MOLECULAR WEIGHT :: 152.26

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Intramuscular

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 100 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

MUTATION DATA

TYPE OF TEST :: Sister chromatid exchange

TEST SYSTEM :: Rodent - hamster Lung

DOSE/DURATION :: 500 umol/L

REFERENCE :: MUREAV Mutation Research. (Elsevier Science Pub. B.V., POB 211, 1000 AE Amsterdam, Netherlands) V.1- 1964- Volume(issue)/page/year: 249,55,1991

Safety Information

Personal Protective Equipment	Eyeshields;Gloves;half-mask respirator (US);multi-purpose combination respirator cartridge (US)
RIDADR	NONH for all modes of transport
WGK Germany	3
RTECS	TK4565000
HS Code	2932999099

Customs

HS Code	2932999099
Summary	2932999099. other heterocyclic compounds with oxygen hetero-atom(s) only. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:20.0%

Articles11

Secondary organic aerosol from alpha-pinene ozonolysis in dynamic chamber system.

Indoor Air 19(4) , 335-45, (2009)

The formation of secondary organic aerosol (SOA) produced from alpha-pinene ozonolysis was examined using a dynamic chamber system that allowed the simulation of ventilated indoor environments. Partic...

Improvement of P450(BM-3) whole-cell biocatalysis by integrating heterologous cofactor regeneration combining glucose facilitator and dehydrogenase in E. coli.

Appl. Microbiol. Biotechnol. 78(1) , 55-65, (2008)

Escherichia coli BL21, expressing a quintuple mutant of P450(BM-3), oxyfunctionalizes alpha-pinene in an NADPH-dependent reaction to alpha-pinene oxide, verbenol, and myrtenol. We optimized the whole-...

Optimization of isonovalal production from alpha-pinene oxide using permeabilized cells of Pseudomonas rhodesiae CIP 107491.

Appl. Microbiol. Biotechnol. 60(5) , 534-40, (2003)

Optimization studies on the synthesis of isonovalal from alpha-pinene oxide by Pseudomonas rhodesiae CIP 107491 operated in a biphasic medium are presented. Three key parameters are identified. The fi...

Synonyms

EINECS 216-869-6

α-Pinene oxide

Alpha-Pinene Oxide

2,3-Epoxypinane

Pinane, 2,3-epoxy-, (-)-

MFCD00066955

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