CAS 927706-57-8|PEPPSI-SIPr catalyst

Introduction：Basic information about CAS 927706-57-8|PEPPSI-SIPr catalyst, including its chemical name, molecular formula, synonyms, physicochemical properties, and safety information, etc.

Table of Contents

1. Names
2. Chemical & Physical Properties
3. Safety Information
4. Articles3

Common Name	PEPPSI-SIPr catalyst
CAS Number	927706-57-8	Molecular Weight	682.48300
Density	/	Boiling Point	/
Molecular Formula	C₃₂H₄₃Cl₃N₃Pd-	Melting Point	/
MSDS	ChineseUSA	Flash Point	/
Symbol	GHS07	Signal Word	Warning

Names

Name	1,3-bis[2,6-di(propan-2-yl)phenyl]imidazolidin-2-ide,3-chloropyridine,dichloropalladium

Chemical & Physical Properties

Molecular Formula	C₃₂H₄₃Cl₃N₃Pd-
Molecular Weight	682.48300
Exact Mass	680.15600
PSA	19.37000
LogP	3.49910
InChIKey	BLDKGTGQENJFON-UHFFFAOYSA-L
SMILES	CC(C)c1cccc(C(C)C)c1N1C=CN(c2c(C(C)C)cccc2C(C)C)C1.Cl[Pd]Cl.Clc1cccnc1

Safety Information

Symbol	GHS07
Signal Word	Warning
Hazard Statements	H302-H312-H332
Precautionary Statements	P280
Personal Protective Equipment	dust mask type N95 (US);Eyeshields;Gloves
RIDADR	NONH for all modes of transport

Articles3

Palladium complexes of N-heterocyclic carbenes as catalysts for cross-coupling reactions--a synthetic chemist's perspective.

Angew. Chem. Int. Ed. Engl. 46 , 2768, (2007)

Palladium-catalyzed C-C and C-N bond-forming reactions are among the most versatile and powerful synthetic methods. For the last 15 years, N-heterocyclic carbenes (NHCs) have enjoyed increasing popula...

Pd-catalyzed aryl amination mediated by well defined, N-heterocyclic carbene (NHC)-Pd precatalysts, PEPPSI.

Chemistry 14 , 2443, (2008)

Pd-N-heterocyclic carbene (NHC)-catalyzed Buchwald-Hartwig amination protocols mediated by Pd-PEPPSI precatalysts is described. These protocols provide access to a range of hindered and functionalized...

Organ, Michael G.; Abdel-Hadi, Mirvat; et al.

Chemistry 12 , 150, (2006)

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