Introduction：Basic information about CAS 169689-05-8|(1S,2S)-(-)-1,2-Diaminocyclohexane-N,N-bis(2-diphenylphosphinobenzoyl), including its chemical name, molecular formula, synonyms, physicochemical properties, and safety information, etc.
| Common Name | (1S,2S)-(-)-1,2-Diaminocyclohexane-N,N-bis(2-diphenylphosphinobenzoyl) |
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| CAS Number | 169689-05-8 | Molecular Weight | 690.748 |
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| Density | / | Boiling Point | 817.0±65.0 °C at 760 mmHg |
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| Molecular Formula | C44H40N2O2P2 | Melting Point | 134-136ºC |
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| MSDS | ChineseUSA | Flash Point | 447.9±34.3 °C |
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Names
| Name | (1S,2S)-(-)-1,2-Diaminocyclohexane-N,N-bis(2-diphenylphosphinobenzoyl) |
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| Synonym | More Synonyms |
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Chemical & Physical Properties
| Boiling Point | 817.0±65.0 °C at 760 mmHg |
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| Melting Point | 134-136ºC |
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| Molecular Formula | C44H40N2O2P2 |
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| Molecular Weight | 690.748 |
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| Flash Point | 447.9±34.3 °C |
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| Exact Mass | 690.256531 |
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| PSA | 85.38000 |
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| LogP | 9.87 |
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| Vapour Pressure | 0.0±2.9 mmHg at 25°C |
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| InChIKey | AXMSEDAJMGFTLR-ZAQUEYBZSA-N |
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| SMILES | O=C(NC1CCCCC1NC(=O)c1ccccc1P(c1ccccc1)c1ccccc1)c1ccccc1P(c1ccccc1)c1ccccc1 |
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Safety Information
| Personal Protective Equipment | Eyeshields;Gloves;type N95 (US);type P1 (EN143) respirator filter |
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| Hazard Codes | Xi:Irritant; |
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| Risk Phrases | 36/37/38 |
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| Safety Phrases | S36-S37-S39 |
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| RIDADR | NONH for all modes of transport |
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Articles5
More Articles
| Asymmetric Transition Metal-Catalyzed Allylic Alkylations. Chem. Rev. 96 , 395, (1996)
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| Asymmetric transition-metal-catalyzed allylic alkylations: applications in total synthesis. Chem. Rev. 103 , 2921, (2003)
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| Trost, B.M. et al. J. Am. Chem. Soc. 124 , 11616, (2004)
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Synonyms
| Trost ligand |
| N,N'-(1S,2S)-1,2-Cyclohexanediylbis[2-(diphenylphosphino)benzamide] |
| MFCD01631274 |
| 2-diphenylphosphanyl-N-[(1S,2S)-2-[(2-diphenylphosphanylbenzoyl)amino]cyclohexyl]benzamide |
| Trost's ligand |
| (S,S)-DACH-phenyl Trost ligand |
| Benzamide, N,N'-(1S,2S)-1,2-cyclohexanediylbis[2-(diphenylphosphino)- |
