Bentonite CAS 1302-78-9

Introduction:Basic information about Bentonite CAS 1302-78-9, including its chemical name, molecular formula, synonyms, physicochemical properties, and safety information, etc.

Bentonite Basic information

Product Name:Bentonite
Synonyms:MONTMORILLONITE;BENTONITE MAGMA;BENTONITE;BENTONITE (SODIUM FORM);FULLERS EARTH;KWK KRYSTAL KLEAR;albagelpremiumusp4444;pengruntu
CAS:1302-78-9
MF:Al2O3.4(SiO2).H2O
MW:360.31
EINECS:215-108-5
Product Categories:UVCBs-inorganic;1302-78-9
Mol File:Mol File

Bentonite Chemical Properties

density 2~3g/cm3
storage temp. Store at room temperature, keep dry and cool
solubility Practically insoluble in water and in aqueous solutions. It swells with a little water forming a malleable mass.
form powder
color Light yellow or green, cream,pink, gray to black solid
Odorodorless, sl. earthy taste
Water Solubility Insoluble in water and forms a colloidal solution.
Merck 14,1055
Exposure limitsACGIH: TWA 1 mg/m3
Dielectric constant8.1(Ambient)
Stability:Stable.
Cosmetics Ingredients FunctionsEMULSION STABILISING
BULKING
ABSORBENT
COLORANT
VISCOSITY CONTROLLING
Cosmetic Ingredient Review (CIR)Bentonite (1302-78-9)
InChIKeyKARVSHNNUWMXFO-UHFFFAOYSA-N
SMILES[Si](=O)=O.[Si](=O)=O.[Si](=O)=O.[Si](=O)=O.[Al]21O[Al](O2)O1.O
CAS DataBase Reference1302-78-9
EPA Substance Registry SystemBentonite (1302-78-9)

Safety Information

Risk Statements 20/22-8
Safety Statements 22-24/25
WGK Germany 3
RTECS CT9450000
TSCA TSCA listed
Storage Class11 - Combustible Solids
Hazardous Substances Data1302-78-9(Hazardous Substances Data)
ToxicityLD50 intravenous in rat: 35mg/kg

Bentonite Usage And Synthesis

DescriptionBentonite is a light yellow, creamy, palebrown or gray to black powder or granules. These chemicals contain 1- 24% crystalline silica (O2Si). Specificgravity (H2O:1)=2.5. Hazard Identification (based onNFPA-704 M Rating System): Health 2, Flammability 1,Reactivity 0. Insoluble in water
Chemical PropertiesBentonite is a light yellow, creamy, palebrown or gray to black powder or granules.
Chemical PropertiesBentonite is a crystalline, claylike mineral, and is available as anodorless, pale buff, or cream to grayish-colored fine powder, whichis free from grit. It consists of particles about 50–150 mm in sizealong with numerous particles about 1–2μm. Microscopic examinationof samples stained with alcoholic methylene blue solutionreveals strongly stained blue particles. Bentonite may have a slightearthy taste.
UsesBentonite is a general purpose additive that is used as a pigment and colorant and to clarify and stabilize wine.
Usesfiller in cosmetics and other products, gel, or solid if dry
UsesAs of Fuller's earth; as emulsifier for oils; as a base for plasters. Pharmaceutic aid (suspending agent).
Usesbentonite (bentonite clay) is used to regulate the viscosity and suspension properties of a cosmetic formulation. It also acts as an overall formula stabilizer. Bentonite’s water-absorption capabilities allow it to form a gelatinous mass. Considered a noncomedogenic raw material, bentonite is a colloidal aluminum silicate clay.
Production MethodsBentonite is a native, colloidal, hydrated aluminum silicate, found inregions of Canada and the USA. The mined ore is processed toremove grit and nonswelling materials so that it is suitable forpharmaceutical applications.
DefinitionA type of claythat is used as an adsorbent in makingpaper. The gelatinous suspension it formswith water is used to bind together thesand for making iron castings. Chemicallybentonite is an aluminosilicate of variablecomposition.
General DescriptionBentonite is comprised primarily of the smectite group (montmorillonite) of clay minerals. It is widely used in various industrial applications such as clarification of edible and mineral oils, paints, cosmetics, and pharmaceuticals. It is also used as an adsorbent for the elimination of pollutants from wastewater.
The swelling property of bentonite is used to produce viscous water suspensions for bonding, plasticizing, and suspending applications. The presence of a large surface area of bentonite is due to the colloidal dispersion of the particles is the main reason for its application as an insecticide carrier, an emulsifier, and an emulsion stabilizer.
Pharmaceutical ApplicationsBentonite is a naturally occurring hydrated aluminum silicate usedprimarily in the formulation of suspensions, gels, and sols, fortopical pharmaceutical applications. It is also used to suspendpowders in aqueous preparations and to prepare cream basescontaining oil-in-water emulsifying agents.
Bentonite may also be used in oral pharmaceutical preparations,cosmetics, and food products. In oral preparations,bentonite, and other similar silicate clays, can be used to adsorbcationic drugs and so retard their release. Adsorbents are alsoused to mask the taste of certain drugs.
Bentonite has been investigated as a diagnostic agent formagnetic resonance imaging.
Therapeutically, bentonite has been investigated as an adsorbentfor lithium poisoning.
Agricultural UsesBentonite, also known as montmorillonite, volcanicclay, soap clay and amargosite, is a soft, plastic, lightcolored,porous rock consisting largely of colloidalsilica. Composed essentially of clay minerals, it swellsextensively when wet. Bentonite belongs chiefly to themontmorillonite group and has two varieties: (a) sodiumbentonite, with a high swelling capacity in water, and(b) calcium bentonite, with negligible swelling capacity.
Bentonite is used variously as a suspending aid, agelatinous slurry to extinguish fire, a paint thickener, andas a sealant for earthen pots. Bentonite is also widely usedin metallurgy, soap manufacture, and in petroleumrefining because of its high decolorizing power andstrong adsorbing capacity.
Agricultural UsesClays exist in many forms, of which montmorillonite isone form. Kaolinite and montmorillonite, which are clayminerals, have different layer structures with differingabilities to absorb and retain water, and to adsorb andexchange cations.
Montmorillonites have an expanding structure (2: 1)and have high cation exchange capacity (80 to 120 mg per100 g). They have abundant black clay soils. Otherminerals in this group are biedellite and nontronite.
Safety ProfilePoison by intravenousroute causing blood clotting. Questionablecarcinogen with experimental tumorigenicdata.
SafetyBentonite is mainly used in topical pharmaceutical formulations buthas also been used in oral pharmaceutical preparations, foodproducts, and cosmetics.
Following oral administration, bentonite is not absorbed fromthe gastrointestinal tract. Bentonite is generally regarded as anontoxic and nonirritant material.
LD50 (rat, IV): 0.035 g/kg
Potential ExposureThis material is used as Fuller’s earth;as a mineral, natural, or synthetic fiber; as an emulsifier foroils; as a base for plasters; in cosmetics, in polishes andabrasives; as a food additive and others. Bentonites are aluminatesilicate and can contain crystalline silica. The contentvaries widely from less than 1% to about 24% .
First aidInhalatio Move person to fresh air. Seek medical attention if necessary. Skin: Wash with water. Eyes:Wash with water as needed. Seek medical attention if necesvsary.
storageBentonite is hygroscopic, and sorption of atmospheric water shouldbe avoided.
Aqueous bentonite suspensions may be sterilized by autoclaving.The solid material may be sterilized by maintaining it at 1708℃ for 1hour after drying at 1008℃.
Bentonite should be stored in an airtight container in a cool, dryplace.
ShippingBentonite is not cited in the DOT Performance-Oriented Packaging Standards.
IncompatibilitiesSubstance is a weak acid in water; avoidcontact with strong alkaline material. Incompatible withoxidizers (chlorates, nitrates, peroxides, permanganates,perchlorates, chlorine, bromine, fluorine, etc.); contact maycause fires or explosions. Keep away from alkaline materials,strong bases, strong acids, oxoacids, epoxides.
IncompatibilitiesAqueous bentonite suspensions retain their viscosity above pH 6,but are precipitated by acids. Acid-washed bentonite does not havesuspending properties. The addition of alkaline materials, such asmagnesium oxide, increases gel formation.
Addition of significant amounts of alcohol to aqueous preparationswill precipitate bentonite, primarily by dehydration of thelattice structure.
Bentonite particles are negatively charged and flocculationoccurs when electrolytes or positively charged suspensions areadded. Bentonite is thus said to be incompatible with strongelectrolytes, although this effect is sometimes used beneficially toclarify turbid liquids.
The antimicrobial efficacy of cationic preservatives may bereduced in aqueous bentonite suspensions, but nonionic and anionicpreservatives are unaffected.
Bentonite is incompatible with acriflavine hydrochloride.
Waste DisposalLand fill disposal.
Regulatory StatusAccepted in Europe as a food additive in certain applications.Included in the FDA Inactive Ingredients Database (oral capsules,tablets and suspensions, topical suspensions, controlled releasetransdermal films and vaginal suppositories). Included in nonparenteralmedicines licensed in the UK. Included in the Canadian Listof Acceptable Non-medicinal Ingredients.

Bentonite Preparation Products And Raw materials

Raw materialsSodium carbonate-->Mineral oil
Preparation ProductsMontmorillonite K10-->anti water resistance to alkali,anti low temperature coating-->SODIUM ALUMINUM OXIDE-->medium temperature Shift catalysts-->medium(high)temperature Shift catalysts-->Oxytocin-->K-CATALYST-->Bentonite,calcium base-->ALUMINUM SILICATE-->clay activated for developer
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