CAS 96-05-9|Allyl methacrylate

Introduction：Basic information about CAS 96-05-9|Allyl methacrylate, including its chemical name, molecular formula, synonyms, physicochemical properties, and safety information, etc.

Table of Contents

1. Names
2. Chemical & Physical Properties
3. Toxicological Information
CHEMICAL IDENTIFICATION
HEALTH HAZARD DATA
ACUTE TOXICITY DATA
4. Safety Information
5. Customs
6. Articles3
7. Synonyms

Common Name	Allyl methacrylate
CAS Number	96-05-9	Molecular Weight	126.15300
Density	0.938 g/mL at 25 °C(lit.)	Boiling Point	59-61 °C43 mm Hg(lit.)
Molecular Formula	C₇H₁₀O₂	Melting Point	-65 °C
MSDS	ChineseUSA	Flash Point	33.9±0.0 °C
Symbol	GHS02, GHS06, GHS08, GHS09	Signal Word	Danger

Names

Name	Allyl methacrylate
Synonym	More Synonyms

Chemical & Physical Properties

Density	0.938 g/mL at 25 °C(lit.)
Boiling Point	59-61 °C43 mm Hg(lit.)
Melting Point	-65 °C
Molecular Formula	C₇H₁₀O₂
Molecular Weight	126.15300
Flash Point	33.9±0.0 °C
Exact Mass	126.06800
PSA	26.30000
LogP	1.29170
Vapour Pressure	4.6 mm Hg ( 20 °C)
Index of Refraction	n20/D 1.436(lit.)
InChIKey	FBCQUCJYYPMKRO-UHFFFAOYSA-N
SMILES	C=CCOC(=O)C(=C)C
Water Solubility	4 g/L (20 ºC)

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :: UD3483000

CHEMICAL NAME :: 2-Propenoic acid, 2-methyl-, 2-propenyl ester

CAS REGISTRY NUMBER :: 96-05-9

BEILSTEIN REFERENCE NO. :: 1747406

LAST UPDATED :: 199710

DATA ITEMS CITED :: 10

MOLECULAR FORMULA :: C7-H10-O2

MOLECULAR WEIGHT :: 126.17

WISWESSER LINE NOTATION :: 1UY1&VO2U1

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: Standard Draize test

ROUTE OF EXPOSURE :: Administration onto the skin

SPECIES OBSERVED :: Rodent - rabbit

REFERENCE :: 85JCAE "Prehled Prumyslove Toxikologie; Organicke Latky," Marhold, J., Prague, Czechoslovakia, Avicenum, 1986 Volume(issue)/page/year: -,371,1986

TYPE OF TEST :: Standard Draize test

ROUTE OF EXPOSURE :: Administration into the eye

SPECIES OBSERVED :: Rodent - rabbit

REFERENCE :: 85JCAE "Prehled Prumyslove Toxikologie; Organicke Latky," Marhold, J., Prague, Czechoslovakia, Avicenum, 1986 Volume(issue)/page/year: -,371,1986 ** ACUTE TOXICITY DATA **

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 70 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: GTPZAB Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1-36, 1957-1992. For publisher information, see MTPEEI Volume(issue)/page/year: 34(8),59,1990

TYPE OF TEST :: LC50 - Lethal concentration, 50 percent kill

ROUTE OF EXPOSURE :: Inhalation

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 1800 mg/m3

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: GTPZAB Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1-36, 1957-1992. For publisher information, see MTPEEI Volume(issue)/page/year: 34(8),59,1990

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 57 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: GTPZAB Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1-36, 1957-1992. For publisher information, see MTPEEI Volume(issue)/page/year: 34(8),59,1990

TYPE OF TEST :: LC50 - Lethal concentration, 50 percent kill

ROUTE OF EXPOSURE :: Inhalation

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 5500 mg/m3

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: GTPZAB Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1-36, 1957-1992. For publisher information, see MTPEEI Volume(issue)/page/year: 34(8),59,1990

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Administration onto the skin

SPECIES OBSERVED :: Rodent - rabbit

DOSE/DURATION :: 500 uL/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: AIHAAP American Industrial Hygiene Association Journal. (AIHA, 475 Wolf Ledges Pkwy., Akron, OH 44311) V.19- 1958- Volume(issue)/page/year: 30,470,1969

Safety Information

Symbol	GHS02, GHS06, GHS08, GHS09
Signal Word	Danger
Hazard Statements	H226-H302-H311-H330-H373-H410
Precautionary Statements	P210-P260-P280-P302 + P352 + P312-P304 + P340 + P310-P370 + P378
Target Organs	Liver
Personal Protective Equipment	Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter
Hazard Codes	T:Toxic
Risk Phrases	R10;R21/22;R23;R50
Safety Phrases	S36/37-S45-S61
RIDADR	UN 2929 6.1/PG 2
WGK Germany	2
RTECS	UD3483000
Packaging Group	II
Hazard Class	6.1
HS Code	2916140000

Customs

HS Code	2916140000
Summary	2916140000. other esters of methacrylic acid. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:80.0%

Articles3

Prediction of the reduced glutathione (GSH) reactivity of dental methacrylate monomers using NMR spectra - Relationship between toxicity and GSH reactivity.

Dent. Mater. J. 28(6) , 722-9, (2009)

It has been established that the toxicity of acrylate and methacrylate monomers is driven by their reactivity towards glutathione (GSH). With this relationship, the objective of this study was to pred...

Glutathione depletion in rat hepatocytes: a mixture toxicity study with alpha, beta-unsaturated esters.

Xenobiotica 31(5) , 295-307, (2001)

1. Glutathione (GSH) depletion is often reported as an early cytotoxic effect, caused by many reactive organic chemicals. In the present study, GSH depletion in primary rat hepatocytes was used as an ...

Subchronic dermal toxicity study of allyl methacrylate in rabbits.

Drug Chem. Toxicol. 5(2) , 165-82, (1982)

A 28-day subchronic dermal toxicity of allyl methacrylate (AMA) was conducted in New Zealand white rabbits. Groups of six male and six female rabbits were treated with the test material at dose levels...

Synonyms

EINECS 202-473-0

MFCD00008592

prop-2-enyl 2-methylprop-2-enoate

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