Fenpropidin CAS 67306-00-7
Introduction：Basic information about Fenpropidin CAS 67306-00-7, including its chemical name, molecular formula, synonyms, physicochemical properties, and safety information, etc.
Fenpropidin Basic information
| Product Name: | Fenpropidin |
| Synonyms: | TERN;SPONSOR;1-(3-(4-(1,1-dimethylethyl)phenyl)-2-methylpropyl)-piperidin;1-(3-(4-(1,1-dimethylethyl)phenyl)-2-methylpropyl)piperidine;1-(3-(4-tert-butylphenyl)-2-methylpropyl)piperidine;cga114900;fenpropidine;patrol |
| CAS: | 67306-00-7 |
| MF: | C19H31N |
| MW: | 273.46 |
| EINECS: | |
| Product Categories: | Alpha sort;E-GAlphabetic;F;FA - FLPesticides;Fungicides;Others;Pesticides&Metabolites |
| Mol File: | 67306-00-7.mol |
Fenpropidin Chemical Properties
| Melting point | 25°C |
| Boiling point | bp0.2 117°; bp0.045 125°; bp0.032 104° |
| density | 0.9112 (rough estimate) |
| vapor pressure | 1.7 x 10-2 Pa (25 °C) |
| refractive index | 1.4900 (estimate) |
| storage temp. | Refrigerator |
| solubility | Chloroform, Ethyl Acetate (Slightly) |
| form | Liquid |
| pka | 10.1 |
| Water Solubility | 530 mg l-1 (pH 7 at 25 °C) |
| color | Clear Colourless |
| Merck | 13,4020 |
| BRN | 5336091 |
| Major Application | agriculture environmental |
| InChI | 1S/C19H31N/c1-16(15-20-12-6-5-7-13-20)14-17-8-10-18(11-9-17)19(2,3)4/h8-11,16H,5-7,12-15H2,1-4H3 |
| InChIKey | MGNFYQILYYYUBS-UHFFFAOYSA-N |
| SMILES | CC(CN1CCCCC1)Cc2ccc(cc2)C(C)(C)C |
| CAS DataBase Reference | 67306-00-7 |
| NIST Chemistry Reference | Fenpropidin(67306-00-7) |
| EPA Substance Registry System | Piperidine, 1-[3-[4-(1,1-dimethylethyl)phenyl]-2-methylpropyl]- (67306-00-7) |
Safety Information
| Hazard Codes | Xn |
| Risk Statements | 21/22-36 |
| Safety Statements | 26-36/37 |
| RIDADR | 2902 |
| WGK Germany | 3 |
| RTECS | TM7292000 |
| HazardClass | 6.1(b) |
| PackingGroup | III |
| HS Code | 29333990 |
| Storage Class | 10 - Combustible liquids |
| Hazard Classifications | Acute Tox. 4 Inhalation Acute Tox. 4 Oral Aquatic Acute 1 Aquatic Chronic 1 Eye Dam. 1 Skin Sens. 1B STOT RE 2 STOT SE 3 |
| Description | fenpropidine, a piperidine derivative,and spiroxamine, a dioxolanemethyleneamine derivativeintroduced in 1996 , belong to the same groupof fungicides. |
| Chemical Properties | Pure phenyl rustidine is light yellow, viscous, odorless liquid. Boiling point:>250°C,70.2°C/1.1Pa.Distribution coefficient KowlgP(25°C,pH 7)=2.9,Henry's constant 10.7 Pa-m3/mol(25°C,calculated). Relative density 0.91(20℃). Solubility in water(g/m3,25℃):530(pH 7),6.2(pH 9);Freely soluble in acetone,ethanol,toluene,n-octanol,n-hexane and other organic solvents. Stable for at least 3 years in closed containers at room temperature, its aqueous solution is UV stable and not hydrolyzed. Strong base,pKa10.1, flash point 156℃. |
| Uses | Fenpropidin is a fungicide. |
| Uses | Agricultural fungicide. |
| Uses | Fenpropidin is both a contact and a systemic fungicide whichprovides effective eradicant control of powdery mildew, rusts and leafblotch in cereal. |
| Definition | ChEBI: A member of the class of piperidines that is N-isobutylpiperidine in which a hydrogen of one of the methyl groups is replaced by a p-tert-butylphenyl group. |
| Hazard | Moderately toxic by ingestion, inhalation,and skin contact. |
| Metabolic pathway | Limited data are available in the open literature. Information presented inthis summary is abstracted from the data evaluation published by thePesticide Safety Directorate (PSD, 1993). Fenpropidin is stable to aqueoushydrolysis and photodegradation. Hydroxylation of the piperidine ring isthe primary metabolic pathway in soil and wheat plants. Hydroxylationand oxidation of one of the methyl groups of the tert-butyl moiety arethe major reactions in rats and lactating goats. The primary metabolicpathways of fenpropidin are presented in Scheme 1. |
| Degradation | Fenpropidin (1)i s stable to hydrolytic degradation (50 °C)in the pH rangeof 3-9 and when exposed to UV light in pH 5 buffer solution. |
Fenpropidin Preparation Products And Raw materials
